Browsing by Subject "Characterization"
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Item A composite tracer analysis approach to reservoir characterization(Texas A&M University, 2005-11-01) Oyerinde, Adedayo StephenIn the quest for production optimization from established resources, there is a continual interest in secondary and tertiary recovery methods. The success of these enhanced recovery methods, however, rely to a large extent on a sound understanding of fluid dynamics and migration paths in the reservoir. To this end, several approaches to reservoir characterization have been put to test with varying degrees of success. The unique ability of tracers to provide direct information on preferential fluid flow paths in the reservoir, and the sensitivity of partitioning tracers to fluid saturation distribution has highlighted the prospects of a detailed reservoir characterization through interwell tracer tests. In a broad sense, analysis of interwell tracer tests fall into two categories, analytical and inverse modeling. While most of the analytical methods are laden with limiting assumptions, the method of moments boasts rigorous formulation and accurate estimates of swept volume and average saturation of bypassed oil. The inverse modeling infers permeability and saturation distribution by matching the tracer response. An extremely effective approach to the inverse modeling methods computes sensitivities based on streamlines. The accurate modeling of tracer flow requires accounting for complex phenomena such as transverse dispersion. Also, it is sometimes desired to model pertinent tracer components through compositional simulation. This necessitates the inclusion of a physical dispersion tensor and, hence, the well established finite difference formulation. In this work, we have coupled the finite difference and streamline simulation techniques for the inversion-based reservoir characterization to take advantage of the robustness of the finite difference formulation and computational efficiency of streamline simulation. We have also extended the formalism of the inversion technique for fluid distribution estimation to scenarios with mobile oil saturations and have attempted integrating the analytical and inverse-modeling techniques to facilitate detailed reservoir characterization. We have demonstrated the feasibility of our approach on both synthetic and field cases.Item Characterization and assessment of uncertainty in San Juan Reservoir Santa Rosa Field(Texas A&M University, 2005-02-17) Becerra, Ernesto JoseThis study proposes a new, easily applied method to quantify uncertainty in production forecasts for a volumetric gas reservoir based on a material balance model (p/z vs. Gp). The new method uses only observed data and mismatches between regression values and observed values to identify the most probable value of gas reserves. The method also provides the range of probability of values of reserves from the minimum to the maximum likely value. The method is applicable even when only limited information is available from a field. Previous methods suggested in the literature require more information than our new method. Quantifying uncertainty in reserves estimation is becoming increasingly important in the petroleum industry. Many current investment opportunities in reservoir development require large investments, many in harsh exploration environments, with intensive technology requirements and possibly marginal investment indicators. Our method of quantifying uncertainty uses a priori information, which could come from different sources, typically from geological data, used to build a static or prior reservoir model. Additionally, we propose a method to determine the uncertainty in our reserves estimate at any stage in the life of the reservoir for which pressure-production data are available. We applied our method to San Juan reservoir at Santa Rosa Field, Venezuela. This field was ideal for this study because it is a volumetric reservoir for which the material balance method, the p/z vs. Gp plot, appears to be appropriate.Item Characterization and interwell connectivity evaluation of Green Rver reservoirs, Wells Draw study area, Uinta Basin, Utah(2009-05-15) Abiazie, Joseph UchechukwuRecent efforts to optimize oil recovery from Green River reservoirs, Uinta Basin, have stimulated the need for better understanding of the reservoir connectivity at the scale of the operational unit. This study focuses on Green River reservoirs in the Wells Draw study area where oil production response to implemented waterflood is poor and a better understanding of the reservoir connectivity is required to enhance future secondary oil recovery. Correlating the sand bodies between well locations in the area remains difficult at 40-acre well spacing. Thus, interwell connectivity of the reservoirs is uncertain. Understanding the reservoir connectivity in the Wells Draw study area requires integration of all static and dynamic data for generation of probabilistic models of the reservoir at the interwell locations. The objective of this study is two-fold. The first objective was to determine reservoir connectivity at the interwell scale in the Wells Draw study area. To achieve this goal, I used well log and perforation data in the Wells Draw study area to produce probabilistic models of net-porosity for four producing intervals: (1) Castle Peak, (2) Lower Douglas Creek, (3) Upper Douglas Creek, and (4) Garden Gulch. The second objective was to find readily applicable methods for determining interwell connectivity. To achieve this goal, I used sandstone net thickness and perforation data to evaluate interwell connectivity in the Wells Draw study area. This evaluation was done to: (1) assess and visualize connectivity, (2) provide an assessment of connectivity for validating / calibrating percolation and capacitance based methods, and (3) determine flow barriers for simulation. The probabilistic models encompass the four producing intervals with a gross thickness of 1,900 ft and enable simulation assessments of different development strategies for optimization of oil recovery in the Wells Draw study area. The method developed for determining interwell connectivity in Wells Draw study area is reliable and suited to the four producing intervals. Also, this study shows that the percolation based method is reliable for determining interwell connectivity in the four producing intervals.Item Characterization of maize testing locations in eastern and southern Africa(Texas A&M University, 2006-08-16) Maideni, Francis W.The region of eastern and southern Africa is very diverse in environments and agronomic practices. The region has one of the highest per capita consumption of maize (Zea mays. L), which is predominantly produced by smallholder farmers. Some important constraints facing these farmers include drought and low fertility. For decades, the International Center for Wheat and Maize Improvement (CIMMYT) has been involved in developing maize genotypes that have high grain yields and are tolerant to drought, low fertility and other important constraints. This germplasm is developed for wide adaptation. However, the development of superior germplasm is significantly affected by interaction between genotypes and the environment (i.e., genotype by environment interaction, GEI). To estimate and understand GEI maize genotypes are evaluated in a range of environments representing as much variability of the target growing areas as possible. Because of dwindling resources needed to conduct testing in the region, it may not be possible to test in all potential target areas. Therefore, a careful process of site selection for testing is essential to improve efficiencies in cultivar testing and deployment. The objective of this research was to characterize the maize testing locations of the eastern and southern Africa region. Historical data from CIMMYT Regional Trials from 1999 to 2003 was used to characterize the environments and estimate genetic parameters. Environmnent and GEI showed consistently high contributions to the total variation observed among genotypes for grain yield. Environment contributed over 60% and sometimes up to 85% of total variation observed. Sequential retrospective pattern analysis (Seqret) was conducted on the adjusted standardized grain yield. A total of 7 groups of environments were identified. Repeatabilites, a measure of the proportion of phenotypic variation that is due to genetic differences, was reduced under stress conditions. The relationship among traits showed that anthesis-silking interval (ASI) is an important selective trait, which can improve selection efficiency for grain yield under stress conditions. Stability analysis provided an opportunity to observe the response and adaptation of genotypes to a wide range of environments. Variety ZM621 was a stable and high yielding genotype.Item Characterization of novel rice germplasm from West Africa and genetic marker associations with rice cooking quality(Texas A&M University, 2006-10-30) Traore, KarimGenetic resource enhancement is the foundation of any good breeding program. Landraces from West Africa, interspecifics between Oryza sativa and Oryza glaberrima and improved lines from the West African Rice Development Association and other research centers were introduced to the Beaumont Rice Research center for in situ evaluation and characterization. Beside the introduction of seeds, milled samples were also introduced for grain chemistry analysis. Field evaluation combined with physicochemical and molecular characterization revealed unique characteristics among African germplasm. New rice for Africa (NERICA) lines performed well in the USA environment. Varieties like Nerica 2, Nerica 3, Nerica 4, and Nerica 5 need more attention because of their superior performance in yield and grain quality. Landraces did not perform well due to their height and late maturity and their resulting problems with lodging. The rapid visco analyzer RVA profiles showed that the cultivar Jaya has unusually strong paste viscosity features. Comparing West Africa samples grown in Cote d??????Ivoire with those grown in Texas, parameters like AA, ASV, Hot, Cool, and CT were not stongly affected by the environment. According to the Stbk value, cultivars grown in Cote d??????Ivoire will cook softer than when they were grown in Texas. The lack of the environmental effect is somewhat surprising considering the difference in latitude, soil types, weather patterns, and management practices between the two locations. Apparent amylose is a key element to characterize a rice cultivar; however certain varieties like Cocodrie and Dixiebelle have similar apparent amylose content but dramatically different functional qualities. A population derived from Cocodrie and Dixiebelle was developed for genotypic and phenotypic analysis of grain chemistry traits that affect functionality. It was concluded that the amount of soluble amylose in the grain had a significant effect on flour pasting properties, even when total apparent amylose content did not vary. Marker association studies revealed that the Waxy microsatellite and the Waxy exon 10 SNP markers were associated with soluble amylose content and RVA characteristics. These markers will speed up the development of new rice cultivars with desirable quality characteristics in West Africa and in the USA.Item Characterization of the Germania Spraberry unit from analog studies and cased-hole neutron log data(Texas A&M University, 2005-11-01) Olumide, Babajide AdelekanThe need for characterization of the Germania unit has emerged as a first step in the review, understanding and enhancement of the production practices applicable within the unit and the trend area in general. Petrophysical characterization of the Germania Spraberry units requires a unique approach for a number of reasons ?? limited core data, lack of modern log data and absence of directed studies within the unit. In the absence of the afore mentioned resources, an approach that will rely heavily on previous petrophysical work carried out in the neighboring ET O??Daniel unit (6.2 miles away), and normalization of the old log data prior to conventional interpretation techniques will be used. A log-based rock model has been able to guide successfully the prediction of pay and non-pay intervals within the ET O??Daniel unit, and will be useful if found applicable within the Germania unit. A novel multiple regression technique utilizing non-parametric transformations to achieve better correlations in predicting a dependent variable (permeability) from multiple independent variables (rock type, shale volume and porosity) will also be investigated in this study. A log data base includes digitized formats of gamma ray, cased hole neutron, limited resistivity and neutron/density/sonic porosity logs over a considerable wide area.Item Designs and methodologies for post-silicon timing characterization(2013-05) Jang, Eun Jung; Abraham, Jacob A.Timing analysis is a key sign-off step in the design of today's chips, but technology scaling introduces many sources of variability and uncertainty that are difficult to model and predict. The result of these uncertainties is a degradation in our ability to predict the performance of fabricated chips, i.e., a lack of model-to-hardware matching. The prediction of circuit performance is the result of a complex hierarchy of models ranging from the basic MOSFET device model to full-chip models of important performance metrics including power, frequency of operation, etc. The assessment of the quality of such models is an important activity, but it is becoming harder and more complex with rising levels of variability and the increase in the number of systematic effects observed in modern CMOS processes. The purpose of this research is (i) to introduce special-purpose test structures that specifically focus on ensuring the accuracy of gate timing models, and (ii) to introduce methods that analyze the extracted information, in the form of path delay measurements, using the proposed test structures. The certification of digital design correctness (the so-called signoff) is based largely on the results of performing Static Timing Analysis (STA), which, in turn, is based entirely on the gate timing models. The proposed test structures compare favorably to alternative approaches; they are far easier to measure than direct delay measurement, and they are much more general than simple ring-oscillator structures. Furthermore, the structures are specified at a high level, allowing them to be synthesized using a standard ASIC place-and-route flow, thus capturing the local layout systematic effects which can sometimes be lost by simpler (e.g., ring oscillator) structures. For the silicon timing analysis, we propose methods that deduce segment delays from the path delay measurements. These estimated segment delays using our methods can be directly compared with the timing models. Therefore, it will be easy to identify the cause of timing mismatches. Deducing segment delays from path delays, however, is not an easy problem. The difficulties associated with deconvolving segment delays from measured path delays come from insufficient sampling points. To overcome this limitation, we first group the segments based on certain characteristics of segments, and adapt Moore-Penrose pseudo-inverse method to approximately solve the segment delays. Secondly, we used equality-constrained least squares methods, which enable us to find a unique and optimized solution of segment delays from underdetermined systems. We also propose another improved test structure that has a built-in test pattern generator, and hence does not require ATPG (Automatic Test Pattern Generation). It is a self-timed circuit, and this feature makes the test structure run as fast as it can. Therefore, measurements can be made under high speed switching conditions. Finally, we can study dynamic effects such as timing effects of different levels of switching activities and voltage drop with the new test structure.Item Development of a heat-balance model for the characterization of wax blockage in flowlines(Texas A&M University, 2006-04-12) Ombu, Ebiaye ValerieThe presence of a blockage in a pipeline will alter the fluid dynamics of a flowing system in terms of the heat, mass and velocity characteristics. The analysis of the fluid dynamics is based on balances taken on the overall system to qualitatively and quantitatively assess the effects of the blockage. Pioneer work in the area of mass and momentum effects of blockages led to the development of blockage type curves useful in characterizing blockages from limited information. This work is an extension of previous work and is based on the application of a simplistic energy balance approach to characterize blockages in pipelines. The resulting heat models for the case of both a partially and fully-blocked flowline correctly predict the effect of wax deposition. Dimensionless temperature-based blockage maps developed here can be used in modeling unique cases where only two of the three necessary conditions are given. The heat model matches results from commercial software within a limited range of restricted flow conditions.Item Genetic pore typing as a means of characterizing reservoir flow units: san andres, sunflower field, terry country, texas(2009-05-15) Humbolt, Aubrey NicoleCarbonate reservoirs are characteristically heterogeneous in reservoir quality and performance owing to the variety of processes that influence pore formation. Additionally, porosity and permeability do not conform to depositional facies boundaries in carbonate reservoirs affected by diagenesis or fracturing; consequently, conventional methods of petrophysical characterization of flow units based on depositional facies are unreliable as predictors of reservoir behavior. We provide an integrated stratigraphic, petrographic, and petrophysical study of the San Andres reservoir at Sunflower field that identifies and quality-ranks flow units on the basis of genetic pore types. A total of 12 full-diameter cores were analyzed revealing three primary depositional facies and cyclical patterns of deposition identified as parasequences. From the cores, 73 samples were chosen for thin sections. Through petrographic analysis, pores were classified using the Ahr 2005 method and four distinct, genetic pore types were identified. Petrophysical rock types were established by identifying which genetic pore types correspond to high poroperm values, and where they occur within the stratigraphic framework of the reservoir. Sixteen coherent plugs were also subjected to mercury injection capillary pressure analysis in order to quantify pore ? pore throat relationships. The data were then evaluated by facies, porosity type, and cycle position using graphical methods, such as k/phi, Winland R35, and Lorenz plots. The results of this study reveal that the most effective way of characterizing petrophysical flow units is the combination of k/phi ratio analyses and genetic pore typing.Item III-V MOSFETs from planar to 3D(2013-08) Xue, Fei, active 2013; Lee, Jack Chung-YeungSi complementary metal-oxide-semiconductor (CMOS) technology has been prospered through continuously scaling of its feature size. As scaling is approaching its physical limitations, new materials and device structures are expected. High electron mobility III-V materials are attractive as alternative channel materials for future post-Si CMOS applications due to their outstanding transport property. High-k dielectrics/metal gate stack was applied to reduced gate leakage current and thus lower the power dissipation. Combining their benefits, great efforts have been devoted to explore III-V/high-k/metal metal-oxide-semiconductor field-effect-transistors (MOSFETs). The main challenges for III-V MOSFETs include interface issues of high-k/III-V, source and drain contact, silicon integration and reliability. A comprehensive study on III-V MOSFETs has been presented here focusing on three areas: 1) III-V/high-k/metal gate stack: material and electrical properties of various high-k dielectrics on III-V substrates have been systematically examined; 2) device architecture: device structures from planar surface channel MOSFETs and buried channel quantum well FETs (QWFETs) to 3D gate-wrapped-around FETs (GWAFETs) and tunneling FETs (TFETs) have been designed and analyzed; 3) fabrication process: process flow has been set up and optimized to build scaled planar and 3D devices with feature size down to 40nm. Potential of high performances have been demonstrated using novel III-V/high-k devices. Effective channel mobility was significantly improved by applying buried channel QWFET structure. Short channel effect control for sub-100nm devices was enhanced by shrinking gate dielectrics, reducing channel thickness and moving from 2D planar to 3D GWAFET structure. InGaAs TFETs have also been developed for ultra-low power application. This research work demonstrates that III-V/high-k/metal MOSFETs with superior device performances are promising candidates for future ultimately scaled logic devices.Item Lithography variability driven cell characterization and layout optimization for manufacturability(2011-05) Ban, Yong Chan; Pan, David Z.; Abraham, Jacob; Touba, Nur; Lucas, Kevin; Orshansky, MichaelStandard cells are fundamental circuit building blocks designed at very early design stages. Nanometer standard cells are prone to lithography proximity and process variations. How to design robust cells under variations plays a crucial role in the overall circuit performance and yield. This dissertation studies five related research topics in design and manufacturing co-optimization in nanometer standard cells. First, a comprehensive sensitivity metric, which seamlessly incorporates effects from device criticality, lithographic proximity, and process variations, is proposed. The dissertation develops first-order models to compute these sensitivities, and perform robust poly and active layout optimization by minimizing the total delay sensitivity to reduce the delay under the nominal process condition and by minimizing the performance gap between the fastest and the slowest delay corners. Second, a new equivalent source/drain (S/D) contact resistance model, which accurately calculates contact resistances from contact area, contact position, and contact shape, is proposed. Based on the impact of contact resistance on the saturation current, robust S/D contact layout optimization by minimizing the lithography variation as well as by maximizing the saturation current without any leakage penalty is performed. Third, this dissertation describes the first layout decomposition methods of spacer-type self-aligned double pattering (SADP) lithography for complex 2D layouts. The favored type of SADP for complex logic interconnects is a two-mask approach using a core mask and a trim mask. This dissertation describes methods for automatically choosing and optimizing the manufacturability of base core mask patterns, generating assist core patterns, and optimizing trim mask patterns to accomplish high quality layout decomposition in SADP process. Fourth, a new cell characterization methodology, which considers a random (line-edge roughness) LER variation to estimate the device performance of a sub-45nm design, is presented. The thesis systematically analyzes the random LER by taking the impact on circuit performance due to LER variation into consideration and suggests the maximum tolerance of LER to minimize the performance degradation. Finally, this dissertation proposes a design aware LER model which claims that LER is highly related to the lithographic aerial image fidelity and the neighboring geometric proximity. With a new LER model, robust LER aware poly layout optimization to minimize the leakage power is performed.Item Low cost alternating current automated characterization system for operational amplifiers(Texas Tech University, 2005-05) Gulas, Scott Matthew; Parten, Michael E.; Cox, RonaldThe purpose of this thesis project was to develop a low-cost automated bench test solution capable of measuring AC (alternating-current) parameters on single and dual packaged voltage-feedback operational amplifiers (op-amps). Electrical properties of the device under test (DUT) are described, along with the methodology used to test these parameters. The design and implementation of the test hardware is covered. A detailed explanation of the test software developed is also included. Finally, a statistical analysis is used to verify that the system is repeatable and accurate in relationship to data taken manually in a bench setup.Item Low cost alternating current automated characterization system for operational amplifiers(2005-05) Gulas, Scott M.; Parten, Michael E.; Cox, Ronald H.The purpose of this thesis project was to develop a low-cost automated bench test solution capable of measuring AC (alternating-current) parameters on single and dual packaged voltage-feedback operational amplifiers (op-amps). Electrical properties of the device under test (DUT) are described, along with the methodology used to test these parameters. The design and implementation of the test hardware is covered. A detailed explanation of the test software developed is also included. Finally, a statistical analysis is used to verify that the system is repeatable and accurate in relationship to data taken manually in a bench setup.Item Mechanistic study of plasma damage to porous low-k : process development and dielectric recovery(2010-05) Shi, Hualiang; Ho, Paul S.; Niu, Qian; Shi, Li; Swift, Jack B.; Yao, ZhenLow-k dielectrics with porosity are being introduced to reduce the RC delay of Cu/low-k interconnect. However, during the O2 plasma ashing process, the porous low-k dielectrics tend to degrade due to methyl depletion, moisture uptake, and densification, increasing the dielectric constant and leakage current. This dissertation presents a study of the mechanisms of plasma damage and dielectric recovery. The kinetics of plasma interaction with low-k dielectrics was investigated both experimentally and theoretically. By using a gap structure, the roles of ion, photon, and radical in producing damage on low-k dielectrics were differentiated. Oxidative plasma induced damage was proportional to the oxygen radical density, enhanced by VUV photon, and increased with substrate temperature. Ion bombardment induced surface densification, blocking radical diffusion. Two analytical models were derived to quantify the plasma damage. Based on the radical diffusion, reaction, and recombination inside porous low-k dielectrics, a plasma altered layer model was derived to interpret the chemical effect in the low ion energy region. It predicted that oxidative plasma induced damage can be reduced by decreasing pore radius, substrate temperature, and oxygen radical density and increasing carbon concentration and surface recombination rate inside low-k dielectrics. The model validity was verified by experiments and Monte-Carlo simulations. This model was also extended to the patterned low-k structure. Based on the ion collision cascade process, a sputtering yield model was introduced to interpret the physical effect in the high ion energy region. The model validity was verified by checking the ion angular and energy dependences of sputtering yield using O2/He/Ar plasma, low-k dielectrics with different k values, and a Faraday cage. Low-k dielectrics and plasma process were optimized to reduce plasma damage, including increasing carbon concentration in low-k dielectrics, switching plasma generator from ICP to RIE, increasing hard mask thickness, replacing O2 by CO2 plasma, increasing CO addition in CO/O2 plasma, and increasing N2 addition in CO2/N2 plasma. By combining analytical techniques with the Kramers-Kronig dispersion relation and quantum chemistry calculation, the origin of dielectric loss was ascribed to the physisorbed water molecules. Post-ash CH4 plasma treatment, vapor silylation process, and UV radiation were developed to repair plasma damage.Item A method for the characterization of white spots in vacuum-arc remelted superalloys(2011-12) Viosca, Alan Lee; Taleff, Eric M.; Beaman, Joseph J.Vacuum-Arc Remelting (VAR) is an important process for manufacturing Ti- and Ni-based superalloys. Currently, the sources and mechanisms behind microstructural anomalies produced in VAR superalloy ingots are not well understood. In order to help understand formation processes, a method of characterizing specific anomalies in VAR ingots is desired. This paper presents a method of characterizing the composition and morphology of anomalies in VAR alloy ingots using a combination of serial sectioning and X-ray fluorescence (XRF) energy dispersive spectroscopy (EDS) techniques. This process is demonstrated on a dirty white spot from an Alloy 718 sample. The white spot of interest was serial polished and 2-D XRF EDS maps were acquired at each polish depth. The EDS maps were then stacked to form a 3-D representation of the white spot. In addition, SEM and optical microscopy techniques were used to further characterize the composition and morphology of the dirty white spot. The dirty white spot is composed of both Ti-enriched and Nb-depleted regions. The 2-D EDS maps acquired with the XRF equipment provided adequate contrast for creating a 3-D representation of the Ti-rich region of the dirty white spot. However, contrast was not sufficient to create a 3-D representation of the Nb-depleted region. The XRF EDS equipment combined with SEM and optical microscopy techniques provided valuable information about the morphology and composition of the Alloy 718 dirty white spot. It is concluded that this dirty white spot was produced by fall-in from either the crown or shelf regions during the VAR process.Item Multi-generational test plan generation and execution in advanced mixed signal controllers(2011-05) Eravelli, Shruti; Gale, Richard O.; Bayne, Stephen B.Most integrated circuits are evolutionary. This is especially true in the realm of system-on-a-chip (SoC) devices that combine multiple functions monolithically. Electronic systems that begin life as an entire printed circuit board often see smaller and smaller chip counts as designs mature. In some cases, functions will be combined into multichip modules that co-locate separate integrated circuits in a single package to provide additional levels of signal integrity and achieve cost reductions. This process continues through stages that culminate in the monolithic integration of these separate chips. The requirement to differentiate similar functions for different customers and applications results in families of SoC’s with similar but not identical capabilities. As parametric and functional testing become larger and larger contributors to total cost, avoiding duplication of effort is a key factor in maintaining competitive position and market share. The strategies involved in achieving economies of scale that can be realized by recognizing the similarities between family members while still providing for differentiation where required is a subject of great interest currently. This work traces the development of test capability in such a family through several generations. An approach that utilizes a motherboard to take advantage of the similarities between family members and is combined with specialized hardware realized in a series of daughter boards, and differentiated software as well is described through several design iterations. Debugging both hardware and software while looking for ways to streamline testing and further reduce test time and cost is detailed. The result is a cost effective approach to advanced device testing that does not compromise performance and provides for acceptable levels of fault coverage.Item Multifunctional cyanate ester/MWNT nanocomposites : processing and characterization(2013-12) Lao, Si Chon; Moon, T. J. (Tess J.); Koo, Joseph H.Tomorrow’s lightweight, high-performance composite systems will be made of structures built with materials that have unprecedented intrinsic properties for performing a wide range of functions, such as EMI shielding, thermal management, flame resistance, lightning strike protection, acoustic damping, and health-monitoring. Current structures require parasitic components, e.g., metal strips, copper wire meshes, strain gauges, and heat sinks to provide these functions. By eliminating parasitic components, future high-performance multifunctional systems can achieve the intended objectives, while maintaining optimum weight, reliability, cost, and fuel efficiency. With the continuing growth of polymer composites in industries, such as aerospace, automotive, and wind energy, research and development on lightweight, high-performance composites that possess extraordinary properties for future multifunctional systems has generated considerable interest and excitement. Recent advances in nanomaterial synthesis and functionalization have shown that tailored property combinations are possible with reduced parasitic content to achieve multifunctionality. Cyanate ester (CE), a class of high-performance thermosetting resins (high T [subscript g], >250°C), has received considerable attention due to its good mechanical properties, thermal stability, flammability properties, ease of process, and volatile-free curing process. Multiwall carbon nanotubes were selected due to their unique combination of excellent mechanical, electrical, and thermal properties. The principal objective of this work is to determine the extent to which several different processing techniques will affect the MWNT dispersion and corresponding nanocomposite properties, such as thermal, flammability, mechanical, and electrical properties. A processing-structure-property relationship, as well as performance of this class of carbon-based CE nanocomposite, will be established. Therefore, a major scientific contribution of this study will be the development and characterization of a novel, multifunctional CE nanocomposite. Different mixing instruments, such as high shear mixer, ultrasonicator, planetary centrifugal mixer, etc. were used to disperse the nanotubes in the cyanate ester resin matrix. Microstructural morphology characterizations by SEM, STEM, and TEM show that various degrees of dispersions of MWNTs were obtained by the different mixing techniques. An attempt to quantify the MWNT dispersion was made. Electrical resistivity of samples processed by both stand mixer and three-roll mill passes the ESD requirement; however, the MWNT percolation thresholds by the two techniques are different. Thermal analysis shows that the addition of the Fe³+ catalyst or the coupling agent lowers the glass transition temperature and degrades the mechanical properties (e.g., storage modulus, tangent of phase angle delta) of the CE resin. On the other hand, processing techniques only affect the mechanical properties of the resin. Thermal stability of CE is only slightly affected by different processing techniques, as well as the addition of MWNTs. Much more significantly, flammability characterization shows that the incorporation of either the Fe³+ catalyst or the coupling agent substantially increases the peak heat release rate (PHRR) relative to the neat CE resin value.Item Scanning probe microscopy study of thin film solar cells(2014-08) Li, Huan, Ph. D.; Shih, Chih-Kang; de Lozanne, Alejandro; Markert, John; Sitz, Greg; Tutuc, EmanuelThin film solar cells, such as CdTe, CuIn [subscript x] Ga [subscript 1-x] Se₂ (CIGS), Cu₂ZnSnS₄ (CZTS) and Cu₂ZnSnSe₄ (CZTSe), have been intensively studied for their unique features and excellent prospect of mass production in industry. The p-n junction is the most critical part of the thin film solar cell and greatly influences the performance. In this thesis work, the p-n junctions and the device layers of multiple kinds of thin film solar cells have been studied by using scanning probe microscopy based techniques. The scanning spreading resistance microscopy (SSRM) has been developed on the cross-section of CdTe solar cells to study the resistance and carrier concentration distribution in different layers of the device. The CdTe sample was cleaved and milled with the argon ion beam to get a flat cross-section. The multiple device layers of the device were identified by the resistance mapping. A high-resistance region around the junction on the CdTe side due to carrier depletion was measured. With the AFM laser illumination, the resistance in the deep depletion region dropped and the resistance across the entire CdTe layer became relatively uniform due to domination of photo-excited carriers. With carriers injected by applying a forward-bias voltage to the working device, the resistance in the deep depletion region decreased and the region moved toward the CdS/CdTe interface. These observed trends and observations are consistent with device physics. We also measured the surface potential and the electric field across the junction using scanning Kelvin probe force microscopy (SKPFM) in the cross-section of the standard CIGS, ZnS(O,OH)/CIGS and the standard CZTSe devices. Both the heterojunction and homojunction situations of the three solar cells were simulated using the PC1D software. The simulation results were compared with the experimental results to analyze the properties of the junction. The comparison results provided the possible ranges of the thickness and carrier concentration of n-CIGS/n-CZTSe layer.Item Studies on submerged cotton fiber growth : induction and characterization, effects of Congo Red and auxin(2003-12) Feng, Rong; Brown, R. Malcolm (Richard Malcolm), 1939-Induction of growth of submerged cotton (Gossypium hirsutum L.) fibers from cultured ovules has been investigated for the first time. Both exogenous plant hormone levels and the age of the ovules at induction play important roles in induction of submerged cotton fiber growth. The diameter of submerged fibers was about same as that of air-grown fibers but was smaller than that of fibers grown in vivo. Submerged fibers were shorter in the fiber length, stronger in the tensile strength, and they had thicker secondary cell walls and smaller crystallite sizes compared with air-grown fibers and fibers in vivo. Helical secondary cell wall thickenings were exclusively found in submerged fibers. Congo Red is a natural dye that has a high affinity for the biopolymer cellulose. The addition of Congo Red to the culture medium had an influence only on submerged cotton fibers and not on air-grown cotton fibers. When Congo Red was applied in the early primary wall stage, fiber cell elongation was inhibited, but amyloplast production was induced. When Congo Red was applied in late primary wall or early secondary wall stage (about 14-16 DPA), the effects were less severe, but a significant increase in birefringence of secondary cell walls was observed. In both conditions of treatment with Congo Red in the primary wall and the secondary wall stages, a "nodulation" occurred on the wall surface. Neither cellobiohydrolase CBH I or CBH II had affinity for the external wall materials, implying that there was no cellulose present or binding sites for CBH had been occupied by Congo Red. X-ray diffraction data showed that Congo Red decreased the crystallite size of cellulose in submerged cotton fibers. The preliminary investigation with auxin (indole-3-acetic acid) depletion in the culture medium was to study whether or not amyloplasts were produced under this condition. No amyloplasts were observed in submerged fibers grown in the auxindepleted medium, but cellulose microfibrils in the secondary cell wall were greatly disorganized. Possibly, indole-3-acetic acid might play an important role in regulating the arrays of microtubules, which, in turn, may help to organize the patterns of cellulose deposition.