Pore-scale numerical modeling of petrophysical properties with applications to hydrocarbon-bearing organic shale

dc.contributor.advisorTorres-Verdín, Carlos
dc.contributor.advisorSepehrnoori, Kamy, 1951-
dc.creatorShabro, Vahiden
dc.date.accessioned2014-01-21T21:21:34Zen
dc.date.accessioned2017-05-11T22:41:08Z
dc.date.available2017-05-11T22:41:08Z
dc.date.issued2013-12en
dc.date.submittedDecember 2013en
dc.date.updated2014-01-21T21:21:34Zen
dc.descriptiontexten
dc.description.abstractThe main objective of this dissertation is to quantify petrophysical properties of conventional and unconventional reservoirs using a mechanistic approach. Unconventional transport mechanisms are described from the pore to the reservoir scale to examine their effects on macroscopic petrophysical properties in hydrocarbon-bearing organic shale. Petrophysical properties at the pore level are quantified with a new finite-difference method. A geometrical approximation is invoked to describe the interstitial space of grid-based images of porous media. Subsequently, a generalized Laplace equation is derived and solved numerically to calculate fluid pressure and velocity distributions in the interstitial space. The resulting macroscopic permeability values are within 6% of results obtained with the Lattice-Boltzmann method after performing grid refinements. The finite-difference method is on average six times faster than the Lattice-Boltzmann method. In the next step, slip flow and Knudsen diffusion are added to the pore-scale method to take into account unconventional flow mechanisms in hydrocarbon-bearing shale. The effect of these mechanisms is appraised with a pore-scale image of Eagle Ford shale as well as with several grain packs. It is shown that neglecting slip flow in samples with pore-throat sizes in the nanometer range could result in errors as high as 2000% when estimating permeability in unconventional reservoirs. A new fluid percolation model is proposed for hydrocarbon-bearing shale. Electrical conductivity is quantified in the presence of kerogen, clay, hydrocarbon, water, and the Stern-diffuse layer in grain packs as well as in the Eagle Ford shale pore-scale image. The pore-scale model enables a critical study of the [delta]LogR evaluation method commonly used with gas-bearing shale to assess kerogen concentration. A parallel conductor model is introduced based on Archie's equation for water conductivity in pores and a parallel conductive path for the Stern-diffuse layer. Additionally, a non-destructive core analysis method is proposed for estimating input parameters of the parallel conductor model in shale formations. A modified reservoir model of single-phase, compressible fluid is also developed to take into account the following unconventional transport mechanisms: (a) slip flow and Knudsen diffusion enhancement in apparent permeability, (b) Langmuir desorption as a source of gas generation at kerogen surfaces, and (c) the diffusion mechanism in kerogen as a gas supply to adsorbed layers. The model includes an iterative verification method of surface mass balance to ensure real-time desorption-adsorption equilibrium with gas production. Gas desorption from kerogen surfaces and gas diffusion in kerogen are the main mechanisms responsible for higher-than-expected production velocities commonly observed in shale-gas reservoirs. Slip flow and Knudsen diffusion marginally enhance production rates by increasing permeability during production.en
dc.description.departmentPetroleum and Geosystems Engineeringen
dc.format.mimetypeapplication/pdfen
dc.identifier.urihttp://hdl.handle.net/2152/22902en
dc.language.isoen_USen
dc.subjectPore-scale modelen
dc.subjectFinite-differenceen
dc.subjectShale-gasen
dc.subjectHydrocarbon-bearing shaleen
dc.subjectElectrical resistivityen
dc.subjectPermeabilityen
dc.subjectFIB-SEMen
dc.subjectLattice-Boltzmann methoden
dc.subjectKnudsen diffusionen
dc.subjectLangmuir desorptionen
dc.subjectDiffusion in kerogenen
dc.subjectOrganic matteren
dc.titlePore-scale numerical modeling of petrophysical properties with applications to hydrocarbon-bearing organic shaleen

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