Browsing by Subject "vadose zone"
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Item An Investigation of Linked Physical And Biogeochemical Processes In Heterogeneous Soils In The Vadose Zone(2012-10-19) Hansen, David JosephChemical dynamics in the vadose zone are poorly understood due to the transient nature of chemical and hydrologic conditions, but are nonetheless critical to understanding contaminant fate and transport. This work explored the effects of soil structure (i.e. layers, lenses) on linked geochemical, hydrological, and microbiological processes under changing hydrologic conditions (e.g. rainfall, introduction of groundwater, and fluctuating water table heights). A homogenized medium-grained sand, homogenized organic-rich loam and a sand-over-loam layered column were constructed for the first series of experiments. The second series of experiments employed two soil columns with lenses that were packed identically with sterilized and untreated sediments. Each consisted of two lenses of organic-rich loam in a medium-grained sand matrix. Lenses were located at different vertical depths and were horizontally offset. In-situ collocated probes collected soil hydrologic and chemical data. In the layered column, enhanced biogeochemical cycling was observed over the texturally homogeneous soil columns. Enumerations of Fe(III) and SO42- reducing microorganisms also show 1-2 orders of magnitude greater community numbers in the layered column. The greatest concentrations of aqueous FeS clusters (FeSaq) were observed in close proximity to the soil interface. To our knowledge, this was the first documentation of FeSaq in partially saturated sediments. Mineral and soil aggregate composite layers were also most abundant near the soil layer interface; the presence of which, likely contributed to an order of magnitude decrease of hydraulic conductivity. In the live lens column, Fe-oxide bands formed at the fringes of the lenses that retarded water flow rates by an order of magnitude compared to the sterilized column. Microbial activity also produced insoluble gases and that led to the creation of a separate gas phase that reduced hydraulic conductivity. This limited the interaction between groundwater with soil-pore waters that led to the formation of geochemically distinct water masses in relatively close proximity to one another. No such changes were observed in the sterilized column. When compared to homogenous columns, the presence of soil heterogeneities altered biogeochemical and hydrologic processes considerably which highlights the need to consider soil heterogeneity in contaminant fate and transport models. These findings suggest that quantifying coupled hydrologic-biogeochemical processes occurring at small scale soil interfaces is critical to accurately describing and predicting chemical changes at the larger system scale.Item Effect of Brush Vegetation on Deep Drainage Using Chloride Mass Balance(2011-02-22) Navarrete Ganchozo, Ronald J.Groundwater use is of fundamental importance to meet rapidly expanding urban, industrial, and agricultural water requirements, particularly in semiarid zones. To quantify the current rate of groundwater recharge is thus a prerequisite for efficient and sustainable groundwater resource management in these dry areas, where such resources are often the key to economic development. Increased groundwater recharge has been documented where native vegetation or forest/shrub land was converted to grassland or pasture, or where the land was cleared for agricultural purposes. The basic argument for increased recharge is that evapotranspiration, primarily interception and transpiration, is higher in shrublands than grasslands. Chloride mass balance (CMB) has been used to estimate ancient recharge, but recharge from recent land-use change has also been documented, specifically where vegetation has been altered and deep-rooted species replaced with shallow-rooted grasses. Chloride concentrations are inversely related to recharge rates: low Clconcentrations indicate high recharge rates as Cl- is leached from the system; high Cl concentrations indicate low recharge rates since Cl- accumulates as a result of evapotranspiration. The objectives were (1) to assess the hypothesis that removal of woody-shrub vegetation and replacement with grasses increases deep drainage, (2) to quantify the amount of deep drainage after land-use change, and (3) to provide science-based data for a better understanding of changing land-use impacts on deep drainage. Eight soils from five locations in the Central Rolling Red Plains near Abilene and Sweetwater were sampled. Each location consisted of a pair of similar soils with contrasting vegetative cover: shrubland and grassland. At each site three to five soil cores were taken as deep as possible and samples were taken by horizon, but horizons were split when their thickness exceeded 0.25 m. Soil Cl- profiles under shrubland at three sites showed that virtually no water escapes beyond the root zone. High Cl- concentrations and inventories reflect soil moisture fluxes that approached 0 mm yr-1 with depth. Evapotranspiration may be largely responsible for Cl- enrichment in those profiles. Surprisingly, soil moisture flux past 200 cm under juniper woodlands was the highest with 2.6 mm yr-1. Evapotranspirative Cl- enrichment in the upper 300 cm was not observed and may suggest a different water uptake mechanism for this plant community. Soil Cl- profiles showed increased recharge rates under grassland vegetation ecosystem. Estimated deep drainage past 200 cm of 0.1 to 1.3 mm yr-1 was observed. Low Cl- concentrations and inventories suggest a leaching environment that may be in response to changes in land use/land cover.Item Scaling Characteristics of Soil Hydraulic Parameters at Varying Spatial Resolutions(2011-08-08) Belur Jana, RaghavendraThis dissertation focuses on the challenge of soil hydraulic parameter scaling in soil hydrology and related applications in general; and, in particular, the upscaling of these parameters to provide effective values at coarse scales. Soil hydraulic properties are required for many hydrological and ecological models at their representative scales. Prediction accuracy of these models is highly dependent on the quality of the model input parameters. However, measurement of parameter data at all such required scales is impractical as that would entail huge outlays of finance, time and effort. Hence, alternate methods of estimating the soil hydraulic parameters at the scales of interest are necessary. Two approaches to bridge this gap between the measurement and application scales for soil hydraulic parameters are presented in this dissertation. The first one is a stochastic approach, based on artificial neural networks (ANNs) applied within a Bayesian framework. ANNs have been used before to derive soil hydraulic parameters from other more easily measured soil properties at matching scales. Here, ANNs were applied with different training and simulation scales. This concept was further extended to work within a Bayesian framework in order to provide estimates of uncertainty in such parameter estimations. Use of ancillary information such as elevation and vegetation data, in addition to the soil physical properties, were also tested. These multiscale pedotransfer function methods were successfully tested with numerical and field studies at different locations and scales. Most upscaling efforts thus far ignore the effect of the topography on the upscaled soil hydraulic parameter values. While this flat-terrain assumption is acceptable at coarse scales of a few hundred meters, at kilometer scales and beyond, the influence of the physical features cannot be ignored. anew upscaling scheme which accounts for variations in topography within a domain was developed to upscale soil hydraulic parameters to hill-slope (kilometer) scales. The algorithm was tested on different synthetically generated topographic configurations with good results. Extending the methodology to field conditions with greater complexities also produced good results. A comparison of different recently developed scaling schemes showed that at hill-slope scales, inclusion of topographic information produced better estimates of effective soil hydraulic parameters at that scale.