Browsing by Subject "structure"
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Item Detection of Gas Hydrates in Garden Banks and Keathley Canyon from Seismic Data(2011-08-08) Murad, IdrisGas hydrate is a potential energy source that has recently been the subject of much academic and industrial research. The search for deep-water gas hydrate involves many challenges that are especially apparent in the northwestern Gulf of Mexico, where the sub-seafloor is a complex structure of shallow salt diapirs and sheets underlying heavily deformed shallow sediments and surrounding diverse minibasins. Here, we consider the effect these structural factors have on gas hydrate occurrence in Garden Banks and Keathley Canyon blocks of the Gulf of Mexico. This was accomplished by first mapping the salt and shallow deformation structures throughout the region using a 2D grid of seismic reflection data. In addition, major deep-rooted faults and shallow-rooted faults were mapped throughout the area. A shallow sediment deformation map was generated that defined areas of significant faulting. We then quantified the thermal impact of shallow salt to better estimate the gas hydrate stability zone (GHSZ) thickness. The predicted base of the GHSZ was compared to the seismic data, which showed evidence for bottom simulating reflectors and gas chimneys. These BSRs and gas chimneys were used to ground-truth the calculated depth of the base of GHSZ. Finally, the calculated GHSZ thickness was used to estimate the volume of the gas hydrate reservoir in the area after determining the most reasonable gas hydrate concentrations in sediments within the GHSZ. An estimate of 5.5 trillion cubic meters of pure hydrate methane in Garden Banks and Keathley Canyon was obtained.Item Experimental study of shear and compaction band formation in berea sandstone(2009-05-15) Herrin, Elizabeth AnneMany field, experimental, and theoretical studies have contributed greatly to our understanding of the occurrence and formation of deformation bands in porous granular materials, but questions remain regarding the mechanics of strain localization, and how the orientation, thickness and internal strain (shear relative to volume change) of deformation bands is influenced by loading history and evolving rock properties. Here we report on triaxial rock deformation experiments using a non-traditional sample geometry to investigate band formation across the brittle-ductile transition. Five-cm diameter cylinders of Berea sandstone were machined with a circular (8.77 cm radius) notch to form a dog-bone sample geometry. In triaxial compression, the sample geometry obviates end-effects without creating heterogeneous stress gradients that can influence localization. Samples were instrumented to measure local strains in the neck region and acoustic emissions (AE), and then shortened to failure at confining pressures of 50 to 250 MPa. Deformation bands formed at all conditions, and photo mosaics of the outer sample surface were used to determine the thickness and orientation of the bands. Band thickness increases from several to tens of mm thickness and the angle between the bands with the shortening axis changes from 35 to 80 degrees, as confining pressure increases from 50 to 250 MPa, respectively. Mechanical data, including local strain measurements through yield, were used to test theoretical models for the onset of localization and formation of deformation bands as an instability in the constitutive description of homogeneous deformation. Generally, theoretical predictions compare favorably with the observed onset of localization determined by marked changes in the AE rate, and are consistent with the formation of compacting shear bands at higher mean stress. Predictions of changes in band orientation with mean stress are largely consistent with observed trends, but deviate from the observed orientation by as much as twenty degrees.Item Scanning tunneling microscopy studies on the structure and stability of model catalysts(2009-05-15) Yang, FanAn atomic level understanding of the structure and stability of model catalysts is essential for surface science studies in heterogeneous catalysis. Scanning tunneling microscopy (STM) can operate both in UHV and under realistic pressure conditions with a wide temperature span while providing atomic resolution images. Taking advantage of the ability of STM, our research focuses on 1) investigating the structure and stability of supported Au catalysts, especially under CO oxidation conditions, and 2) synthesizing and characterizing a series of alloy model catalysts for future model catalytic studies. In our study, Au clusters supported on TiO2(110) have been used to model supported Au catalysts. Our STM studies in UHV reveal surface structures of TiO2(110) and show undercoordinated Ti cations play a critical role in the nucleation and stabilization of Au clusters on TiO2(110). Exposing the TiO2(110) surface to water vapor causes the formation of surface hydroxyl groups and subsequently alters the growth kinetics of Au clusters on TiO2(110). STM studies on Au/TiO2(110) during CO oxidation demonstrate the real surface of a working catalyst. Au clusters supported on TiO2(110) sinter rapidly during CO oxidation, but are mostly stable in the single component reactant gas, either CO or O2. The sintering kinetics of supported Au clusters has been measured during CO oxidation and gives an activation energy, which supports the mechanism of CO oxidation induced sintering. CO oxidation was also found to accelerate the surface diffusion of Rh(110). Our results show a direct correlation between the reaction rate of CO oxidation and the diffusion rate of surface metal atoms. Synthesis of alloy model catalysts have also been attempted in our study with their structures successfully characterized. Planar Au-Pd alloy films has been prepared on a Rh(100) surface with surface Au and Pd atoms distinguished by STM. The growth of Au-Ag alloy clusters have been studied by in-situ STM on a cluster-to-cluster basis. Moreover, the atomic structure of a solution-prepared Ru3Sn3 cluster has been resolved on an ultra-thin silica film surface. The atomic structure and adsorption sites of the ultrathin silica film have also been well characterized in our study.Item Structural and Aerodynamic Interaction Computational Tool for Highly Reconfigurable Wings(2011-10-21) Eisenbeis, Brian JosephMorphing air vehicles enable more efficient and capable multi-role aircraft by adapting their shape to reach an ideal configuration in an ever-changing environment. Morphing capability is envisioned to have a profound impact on the future of the aerospace industry, and a reconfigurable wing is a significant element of a morphing aircraft. This thesis develops two tools for analyzing wing configurations with multiple geometric degrees-of-freedom: the structural tool and the aerodynamic and structural interaction tool. Linear Space Frame Finite Element Analysis with Euler-Bernoulli beam theory is used to develop the structural analysis morphing tool for modeling a given wing structure with variable geometric parameters including wing span, aspect ratio, sweep angle, dihedral angle, chord length, thickness, incidence angle, and twist angle. The structural tool is validated with linear Euler-Bernoulli beam models using a commercial finite element software program, and the tool is shown to match within 1% compared to all test cases. The verification of the structural tool uses linear and nonlinear Timoshenko beam models, 3D brick element wing models at various sweep angles, and a complex wing structural model of an existing aircraft. The beam model verification demonstrated the tool matches the Timoshenko models within 3%, but the comparisons to complex wing models show the limitations of modeling a wing structure using beam elements. The aerodynamic and structural interaction tool is developed to integrate a constant strength source doublet panel method aerodynamic tool, developed externally to this work, with the structural tool. The load results provided by the aerodynamic tool are used as inputs to the structural tool, giving a quasi-static aeroelastically deflected wing shape. An iterative version of the interaction tool uses the deflected wing shape results from the structural tool as new inputs for the aerodynamic tool in order to investigate the geometric convergence of an aeroelastically deflected wing shape. The findings presented in this thesis show that geometric convergence of the deflected wing shape is not attained using the chosen iterative method, but other potential methods are proposed for future work. The tools presented in the thesis are capable of modeling a wide range of wing configurations, and they may ultimately be utilized by Machine Learning algorithms to learn the ideal wing configuration for given flight conditions and develop control laws for a flyable morphing air vehicle.Item Supramolecules with dimolybdenum or chiral dirhodium units(Texas A&M University, 2007-04-25) Yu, RongminThis dissertation concerns the syntheses and characterization of supramolecules with quadruply bonded Mo2 4+ units, Mo2(DAniF)3 + (DAniF = N,N'-di-p-anisylformamidinate) or cis- Mo2(DAniF)2 2+, and chiral organometallic Rh2 4+ units, including racemic cis-Rh2(C6H4PPh2)2 2+ and pure enantiomers of cis-Rh2(C6H4PPh2)2 2+. Molecular pairs of dimolybdenum units in which Mo2(DAniF)3 + units are linked by cyclic diamidate anions or dioxolene anions have been investigated. Linkers impact the electronic communication between the dimetal units in various ways. The symmetry and the energy of the frontier orbitals of the linker are among the factors which influence significantly the properties of the molecular pairs. Nature has provided us a great opportunity to study quantitatively the equilibrium between neutral supramolecules with cis-Mo2(DAniF)2 2+ units. Studies of the concentrationdependent and temperature-dependent equilibria between a molecular triangle and square as well as a molecular loop and triangle using 1H and 19F NMR spectra provide quantitative values for the thermodynamic equilibrium constant K, as well as ??????H????, and ??????S???? for the equilibria. The synthesis and characterization supramolecular compounds containing chiral cis- Rh2(C6H4PPh2)2 2+ units, including three racemic triangles and pure enantiomers of three triangles, a carceplex with T symmetry and two loops are also presented.Item Thermal and Structural Constraints on the Tectonic Evolution of the Idaho-Wyoming-Utah Thrust Belt(2013-08-09) Chapman, Shay MichaelThe timing of motion on thrust faults in the Idaho-Wyoming-Utah (IWU) thrust belt comes from synorogenic sediments, apatite thermochronology and direct dating of fault rocks coupled with good geometrical constraints of the subsurface structure. The thermal history comes from the analyses of apatite thermochronology, thermal maturation of hydrocarbon source rocks and isotope analysis of fluid inclusions from syntectonic veins. New information from zircon fission track and zircon (U-Th)/He analysis provide constraints on the thermal evolution of the IWU thrust belt over geological time. These analyses demonstrate that the time-temperature pathway of the rocks sampled never reached the required conditions to reset the thermochronometers necessary to provide new timing constraints. Previous thermal constraints for maximum temperatures of IWU thrust belt rocks, place the lower limit at ~110?C and the upper limit at ~328?C. New zircon fission track results suggest an upper limit at ~180?C for million year time scales. ID-TIMS and LA-ICPMS of syntectonic calcite veins suggest that new techniques for dating times of active deformation are viable given that radiogenic isotope concentrations occur at sufficient levels within the vein material.