Browsing by Subject "magnetic properties"
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Item Cyanide clusters of ReII with 3d metal ions and their magnetic properties: incorporating anisotropic ions into metal-cyanide clusters with high spin magnetic ground states(Texas A&M University, 2005-08-29) Schelter, Eric JohnClusters of metal ions that possess large numbers of magnetically coupled unpaired electrons have attracted much interest in recent years due to their fascinating magnetic behavior. With an appreciable component of magnetic anisotropy, these large-spin paramagnetic molecules can exhibit an energy barrier to inversion of their magnetic dipole, leading to spontaneous magnetization and magnetic hysteresis below a critical temperature. Since this behavior is a property of an individual clusters rather than a collection of molecules, this phenomenon has been dubbed ??Single Molecule Magnetism??. Our approach to the study of new high-spin systems has been to exert a measure of synthetic control in the preparation of clusters. Specifically we are employing highly anisotropic metal ions with the anticipation that these ions would engender large overall magnetic anisotropy in the resulting clusters. The first step in this process was the development of the chemistry of two new d5 ReII (S = ??) complexes, namely [ReII(triphos)(CH3CN)3][PF6]2 and [Et4N][ReII(triphos)(CN)3]. The magnetic, optical and electrochemical properties were studied and theoretical models were developed to describe the origin of the large temperature independent paramagnetism that was observed. Next, we successfully employed transition metal cyanide chemistry using the ReII building blocks to prepare a family of isostructural, cubic clusters of the general formula {[MCl]4[Re(triphos)(CN)3]4} M = Mn, Fe, Co, Ni, Cu, Zn whose 3d ions adopt local tetrahedral geometries. Within the clusters, magnetic exchange is observed between the paramagnetic ions, which has been modeled using an Ising exchange model to account for the dominating anisotropy of the ReII ion. Despite the high pseudo-symmetry of the clusters (Td), this work has yielded a rare example of a metal-cyanide single molecule magnet, {[MCl]4[Re(triphos)(CN)3]4} with an S = 8 ground state, D = -0.39 cm-1 and an effective energy barrier for magnetization reversal of Ueff = 8.8 cm-1. The elucidation of this family of isostructural clusters has also allowed us to pursue fundamental work on the structure/property relationships of the exotic, paramagnetic ReII ion. As the clusters are soluble, stable compounds, the future of this chemistry lies in the development of a true building-block approach to ??super-clusters?? that exhibit very high ground state spin values.Item High temperature, permanent magnet biased, homopolar magnetic bearing actuator(Texas A&M University, 2006-10-30) Hossain, Mohammad AhsanThe EEC (Electron Energy Corporation) in conjunction with the National Aeronautics and Space Administration is researching the magnetic bearings for an alternative to conventional journal or ball bearings. The purpose of this research was to design and develop a high-temperature (1000????F) hybrid Magnetic Bearing using High Temperature Permanent Magnets (HTPM), developed by the EEC for high performance jet engines at high speeds that supply loads of 500 lbf. Another objective is to design and build a test rig fixture to measure the load capacity of the designed bearing. The permanent magnet bias of the Homopolar radial magnetic bearing reduces the amount of current required for magnetic bearing operation. This reduces the power loss due to the coil current resistance and improves the system efficiency because the magnetic field of the HTPM can suspend the major portion of the static load on bearing. A high temperature radial magnetic bearing was designed via an iterative search employing 3D finite element based electromagnetic field simulations. The bearing was designed to produce 500 lbf of force at 1000????F and the design weight is 48 lbs. The bias flux of the Homopolar radial bearing is produced by EEC HTPM to reduce the related ohmic losses of an electromagnetic circuit significantly. An experimental procedure was developed to measure actual load capacity of the designed bearing at the test rig. All the results obtained from the experiment were compiled and analyzed to determine the relation between bearing force, applied current and temperature.Item Magnetic structure of Loihi Seamount, an active hotspot volcano in the Hawaiian Island chain(Texas A&M University, 2004-09-30) Lamarche, Amy J.The use of geophysical techniques to image the interiors of active volcanoes can provide a better understanding of their structure and plumbing. The need for such information is especially critical for undersea volcanoes, whose environment makes them difficult to investigate. Because undersea volcanoes are made up of highly magnetic basaltic rock, it is possible to use variations in the magnetic field to explore the internal structure of such edifices. This study combines magnetic survey data from 12 research cruises to make a magnetic anomaly map of volcanically active Loihi, located in the Hawaiian Island chain. NRM intensities and susceptibility measurements were measured from recovered rock samples and suggest that magnetic properties of Loihi are widely varied (NRM intensities range from 1-157 A/m and susceptibilities from 1.26 x 10-3 to 3.62 x 10-2 S.I.). The average NRM intensity is 26 A/m. The size and strength of magnetic source bodies were determined by using various modeling techniques. A strongly magnetized shield can explain most of the anomaly with a large nonmagnetic zone inside, beneath the summit. Prominent magnetic highs are located along Loihi's north and south rift zone dikes and modeling solutions suggest strongly magnetized source bodies in these areas as well as a thin, magnetic layer atop the nonmagnetic zone. The strong magnetic anomalies found along the volcano's rift zones cannot be readily attributed to recent lava flows at the surface. Instead, the source bodies must continue several kilometers in depth to give reasonable magnetization values and are interpreted as dike intrusions. Nonmagnetic anomalies at the summit and south of the summit suggest the presence of a magma system. The model solution suggests Loihi is an inhomogeneously magnetized seamount with highly magnetic dike intrusions along the rift zones with a nonmagnetic body at its center overlain with a magnetic layer.