Browsing by Subject "dielectric constant"
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Item Calibration of water content reflectometer in Rocky Mountain arsenal soil(2009-08) Tang, Yucao; Zornberg, Jorge G.; El Mohtar, Chadi S.This paper describes how water content reflectometers (WCRs) were analyzed to develop a calibration equation. Time domain reflectometry (TDR) technique is the most prevalent method in in-situ moisture monitoring; and WCR is a type of low frequency TDR sensors, which is sensitive to soil type. Developing soil-specific calibration and investigating different environmental effects on WCR calibration is important. This study focused on investigation of the soil dry density and temperature effects on WCR calibration in RMA soil. Two series of tests to develop soil-specific calibration with dry density and temperature offset were conducted. Results from testing program showed that WCR response was positive related to volumetric water content, dry density, and temperature. Equations were developed to illustrate the response-density-temperature-moisture relation. Application to a field site was also presented to illustrate the difference in volumetric water contents obtained by using manufacturer method and the calibration procedure drawn in this paper.Item Electric field manipulation of polymer nanocomposites: processing and investigation of their physical characteristics(2009-05-15) Banda, SumanthResearch in nanoparticle-reinforced composites is predicated by the promise for exceptional properties. However, to date the performance of nanocomposites has not reached its potential due to processing challenges such as inadequate dispersion and patterning of nanoparticles, and poor bonding and weak interfaces. The main objective of this dissertation is to improve the physical properties of polymer nanocomposites at low nanoparticle loading. The first step towards improving the physical properties is to achieve a good homogenous dispersion of carbon nanofibers (CNFs) and single wall carbon nanotubes (SWNTs) in the polymer matrix; the second step is to manipulate the well-dispersed CNFs and SWNTs in polymers by using an AC electric field. Different techniques are explored to achieve homogenous dispersion of CNFs and SWNTs in three polymer matrices (epoxy, polyimide and acrylate) without detrimentally affecting the nanoparticle morphology. The three main factors that influence CNF and SWNT dispersion are: use of solvent, sonication time, and type of mixing. Once a dispersion procedure is optimized for each polymer system, the study moves to the next step. Low concentrations of well dispersed CNFs and SWNTs are successfully manipulated by means of an AC electric field in acrylate and epoxy polymer solutions. To monitor the change in microstructure, alignment is observed under an optical microscope, which identifies a two-step process: rotation of CNFs and SWNTs in the direction of electric field and chaining of CNFs and SWNTs. In the final step, the aligned microstructure is preserved by curing the polymer medium, either thermally (epoxy) or chemically (acrylate). The conductivity and dielectric constant in the parallel and perpendicular direction increased with increase in alignment frequency. The values in the parallel direction are greater than the values in the perpendicular direction and anisotropy in conductivity increased with increase in AC electric field frequency. There is an 11 orders magnitude increase in electrical conductivity of 0.1 wt% CNF-epoxy nanocomposite that is aligned at 100 V/mm and 1 kHz frequency for 90 minutes. Electric field magnitude, frequency and time are tuned to improve and achieve desired physical properties at very low nanoparticle loadings.Item Wireless Monitoring of Railway Embankments(2010-07-14) Dantal, Vishal S.Landslides are one of the most dangerous geological hazards. In the United States, landslides cause a damage of $ 3.5 billion and kill 25 to 50 people annually. Shallow landslides occurring near any transportation facilities (railways and highways) can cause economic loss and disturbance of services which lead to indirect economic loss. It also increases the maintenance cost of those facilities. Hence, facilities located near a shallow landslide prone area should be monitored so as to avoid any catastrophic damages. Soil moisture and movement of the soil mass are prime indicators of potential shallow slide movements. This assessment of wireless instruments considers a variety of devices ranging from devices for monitoring tilt and moisture at specific points in the soil mass to ground penetrating radar (GPR), which can give indications of moisture accumulation in soils over a wide spatial extent. For this assessment study, a low cost MEMS accelerometer was selected for measuring tilts and motions. And EC type soil moisture sensor was selected to measure soil moisture content of embankments. The instrumentation of railway embankments works effectively and cheaply when a suspected problem area has already been identified and monitoring is needed over a limited spatial extent. This makes the monitoring system highly localized which often fails to cover potentially new failure prone areas. It is not feasible to use this approach to monitor soil conditions along the entire alignment of the railway. Therefore, another approach, GPR, is defined and explained in this study. GPR measures the dielectric constant value for any given material including soils. In soils, the dielectric constant value depends on the volumetric amount of water content present in a soil. Due to moisture infiltration, there is a reduction in suction value on embankment which indicates a decrease in shear strength of slope. Therefore, a correlation between suction and dielectric constant value is formulated in this study using Complex Refractive index model/Time propagation (CRIM/TP) model for soils. To validate this theoretical correlation, a laboratory study was conducted on pure kaolinite and on normal soil. For pure kaolinite this correlation proves beneficial while, for other type of soil, the correlation was off due to the limitations in filter paper test to measure suction below 2.5pF.Item Zirconium-doped tantalum oxide high-k gate dielectric films(Texas A&M University, 2005-02-17) Tewg, Jun-YenA new high-k dielectric material, i.e., zirconium-doped tantalum oxide (Zr-doped TaOx), in the form of a sputter-deposited thin film with a thickness range of 5-100 nm, has been studied. Important applications of this new dielectric material include the gate dielectric layer for the next generation metal-oxide-semiconductor field effect transistor (MOSFET). Due to the aggressive device scaling in ultra-large-scale integrated circuitry (ULSI), the ultra-thin conventional gate oxide (SiO2) is unacceptable for many practical reasons. By replacing the SiO2 layer with a high dielectric constant material (high-k), many of the problems can be solved. In this study, a novel high-k dielectric thin film, i.e., TaOx doped with Zr, was deposited and studied. The film?s electrical, chemical, and structural properties were investigated experimentally. The Zr dopant concentration and the thermal treatment condition were studied with respect to gas composition, pressure, temperature, and annealing time. Interface layer formation and properties were studied with or without an inserted thin tantalum nitride (TaNx) layer. The gate electrode material influence on the dielectric properties was also investigated. Four types of gate materials, i.e., aluminum (Al), molybdenum (Mo), molybdenum nitride (MoN), and tungsten nitride (WN), were used in this study. The films were analyzed with ESCA, XRD, SIMS, and TEM. Films were made into MOS capacitors and characterized using I-V and C-V curves. Many promising results were obtained using this kind of high-k film. It is potentially applicable to future MOS devices.