Browsing by Subject "ceramic"
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Item Mechanics of Light Weight Proppants: A Discrete Approach(2012-07-16) Kulkarni, MandarProppants are a specific application of granular materials used in oil/gas well stimulation. Employment of hard and soft particle mixtures is one of the many approaches availed by the industry to improve fracture resistance and the stability of the granular pack in the hydraulic fracture. Current industrial practices of proppant characterization involve long term and expensive conductivity tests. However, the mechanics governing the proppant pack response, in particular the effects due to material, shape and size of particles on the pack porosity, stiffness and particle fragmentation are not understood clearly. The present research embodies analytical and experimental approach to model hard (ceramic) and soft (walnut shell and/or pure aluminum) proppant mixtures by taking into account polydispersity in size, shape and material type of individual particles. The hydraulic fracture condition is represented through confined compression and flowback loads. The particle interactions clearly illustrate changes in pore space as a function of pressure, mixture composition and friction. Single particle compression tests on individual particles are carried out to obtain mechanical properties which are incorporated into the finite element models and are further correlated with the compression/crush response of the mixture. The proppant pack stiffness and particle fragmentation depends strongly on the mixture composition as illustrated in the models and experiments. The flowback models demonstrated that the formation of a stable arch is essential to pack stability. Additional variables that enhance flowback resistance are identified as: addition of softer particles to a pack, softer rock surfaces and higher inter-particle friction. The computational studies also led to the discovery of better, and more efficient pack compositions such as - short and thin pure Al needles/ceramic and the pistachio shells/ceramic mixtures. These analytical results have generated great interest and are engaged in the design of experiments to formulate future proppant pack mixtures at Baker Hughes Pressure Pumping, Tomball, TX.Item Sintered Bentonite Ceramics for the Immobilization of Cesium- and Strontium-Bearing Radioactive Waste(2010-07-14) Ortega, Luis H.The Advanced Fuel Cycle Initiative (AFCI) is a Department of Energy (DOE) program, that has been investigating technologies to improve fuel cycle sustainability and proliferation resistance. One of the program's goals is to reduce the amount of radioactive waste requiring repository disposal. Cesium and strontium are two primary heat sources during the first 300 years of spent nuclear fuel's decay, specifically isotopes Cs-137 and Sr-90. Removal of these isotopes from spent nuclear fuel will reduce the activity of the bulk spent fuel, reducing the heat given off by the waste. Once the cesium and strontium are separated from the bulk of the spent nuclear fuel, the isotopes must be immobilized. This study is focused on a method to immobilize a cesium- and strontium-bearing radioactive liquid waste stream. While there are various schemes to remove these isotopes from spent fuel, this study has focused on a nitric acid based liquid waste. The waste liquid was mixed with the bentonite, dried then sintered. To be effective sintering temperatures from 1100 to 1200 degrees C were required, and waste concentrations must be at least 25 wt%. The product is a leach resistant ceramic solid with the waste elements embedded within alumino-silicates and a silicon rich phase. The cesium is primarily incorporated into pollucite and the strontium into a monoclinic feldspar. The simulated waste was prepared from nitrate salts of stable ions. These ions were limited to cesium, strontium, barium and rubidium. Barium and rubidium will be co-extracted during separation due to similar chemical properties to cesium and strontium. The waste liquid was added to the bentonite clay incrementally with drying steps between each addition. The dry powder was pressed and then sintered at various temperatures. The maximum loading tested is 32 wt. percent waste, which refers to 13.9 wt. percent cesium, 12.2 wt. percent barium, 4.1 wt. percent strontium, and 2.0 wt. percent rubidium. Lower loadings of waste were also tested. The final solid product was a hard dense ceramic with a density that varied from 2.12 g/cm3 for a 19% waste loading with a 1200 degrees C sintering temperature to 3.03 g/cm3 with a 29% waste loading and sintered at 1100 degrees C. Differential Scanning Calorimetry and Thermal Gravimetric Analysis (DSC-TGA) of the loaded bentonite displayed mass loss steps which were consistent with water losses in pure bentonite. Water losses were complete after dehydroxylation at ~650 degrees C. No mass losses were evident beyond the dehydroxylation. The ceramic melts at temperatures greater than 1300 degrees C. Light flash analysis found heat capacities of the ceramic to be comparable to those of strontium and barium feldspars as well as pollucite. Thermal conductivity improved with higher sintering temperatures, attributed to lower porosity. Porosity was minimized in 1200 degrees C sinterings. Ceramics with waste loadings less than 25 wt% displayed slump, the lowest waste loading, 15 wt% bloated at a 1200 degrees C sintering. Waste loading above 25 wt% produced smooth uniform ceramics when sintered >1100 degrees C. Sintered bentonite may provide a simple alternative to vitrification and other engineered radioactive waste-forms.