Browsing by Subject "aggregates"
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Item An Investigation of Linked Physical And Biogeochemical Processes In Heterogeneous Soils In The Vadose Zone(2012-10-19) Hansen, David JosephChemical dynamics in the vadose zone are poorly understood due to the transient nature of chemical and hydrologic conditions, but are nonetheless critical to understanding contaminant fate and transport. This work explored the effects of soil structure (i.e. layers, lenses) on linked geochemical, hydrological, and microbiological processes under changing hydrologic conditions (e.g. rainfall, introduction of groundwater, and fluctuating water table heights). A homogenized medium-grained sand, homogenized organic-rich loam and a sand-over-loam layered column were constructed for the first series of experiments. The second series of experiments employed two soil columns with lenses that were packed identically with sterilized and untreated sediments. Each consisted of two lenses of organic-rich loam in a medium-grained sand matrix. Lenses were located at different vertical depths and were horizontally offset. In-situ collocated probes collected soil hydrologic and chemical data. In the layered column, enhanced biogeochemical cycling was observed over the texturally homogeneous soil columns. Enumerations of Fe(III) and SO42- reducing microorganisms also show 1-2 orders of magnitude greater community numbers in the layered column. The greatest concentrations of aqueous FeS clusters (FeSaq) were observed in close proximity to the soil interface. To our knowledge, this was the first documentation of FeSaq in partially saturated sediments. Mineral and soil aggregate composite layers were also most abundant near the soil layer interface; the presence of which, likely contributed to an order of magnitude decrease of hydraulic conductivity. In the live lens column, Fe-oxide bands formed at the fringes of the lenses that retarded water flow rates by an order of magnitude compared to the sterilized column. Microbial activity also produced insoluble gases and that led to the creation of a separate gas phase that reduced hydraulic conductivity. This limited the interaction between groundwater with soil-pore waters that led to the formation of geochemically distinct water masses in relatively close proximity to one another. No such changes were observed in the sterilized column. When compared to homogenous columns, the presence of soil heterogeneities altered biogeochemical and hydrologic processes considerably which highlights the need to consider soil heterogeneity in contaminant fate and transport models. These findings suggest that quantifying coupled hydrologic-biogeochemical processes occurring at small scale soil interfaces is critical to accurately describing and predicting chemical changes at the larger system scale.Item Early age delamination in concrete pavements made with gravel aggregates(2009-06-02) Liu, JuanyuGravel aggregates had been used extensively in the Houston District of Texas Department of Transportation (TxDOT) for continuously reinforced concrete pavements construction for many years. However, some of these pavements have been subject to early age delamination and eventual spalling damage. Therefore, a series of studies funded by TxDOT since the early 1990's has been conducted to gain a better understanding of mechanisms, material properties, and construction practices, and to provide guidelines and recommendations for minimizing early-age delamination in concrete pavements made with gravel aggregates. In this study, a test protocol to measure the bond strength between aggregates and cement mortar was established, and the effects of different material and construction parameters on the bond strength of concrete at early ages using a fractional factorial design were investigated. The significances of each factor to achieve better bonding performance were determined, and the optimum design combination was subsequently chosen and validated. Geometric parameters were proposed to characterize aggregate shape properties relative to bonding performance with the facilitation of the Aggregate Imaging System. A rating system based on utility theory was developed to evaluate the overall contribution of aggregate properties (i.e. physical, geometric, and chemical) to the concrete bonding capability and the feasibility of certain mixture design combinations. As for theoretical representation of the bond strength across the interfacial transition zone, a model of interfacial fracture energy between aggregate and mortar that represents the energy necessary to create a crack along the interface was formulated. This model built the connection between concrete properties at the meso-level (represented by the interfacial fracture energy between aggregate and mortar) and the macro-level (represented by fracture toughness of concrete and significant influencing materials and construction factors). In addition, the moisture effects on stress development of concrete pavements at early ages using field data as inputs were numerically simulated, and a fracture mechanics-based approach was used to predict the occurrence of delamination. A delamination detection protocol for the field was developed to explore the feasibility and potential of utilizing Ground Penetration Radar technology in delamination detection. Research findings from laboratory investigation, field testing, theoretical modeling, and numerical analysis were further validated through field test sections, and the associated framework for delamination guidelines was established.Item Evaluation of moisture damage within asphalt concrete mixes(Texas A&M University, 2004-09-30) Shah, Brij D.Pavements are a major part of the infrastructure in the United States. Moisture damage of these pavements is a significant problem. To predict and prevent this kind of moisture damage a great deal of research has been performed on this issue in past. This study validates an analytical approach based on surface energy aimed at assessing moisture damage. Two types of bitumen and three aggregates are evaluated in the study. The two types of bitumen represent very different chemical extremes and the three aggregates (a limestone, siliceous gravel, and granite) represent a considerable range in mineralogy. Moisture damage was monitered as a change in dynamic modulus with load cycles. The analysis demonstrates the need to consider mixture compliance as well as bond energy in order to predict moisture damage. Mixtures with the two types of bitumen and each aggregate with and without hydrated lime were evaluated. The hydrated lime substantially improved the resistance of the mixture to moisture damage.