Browsing by Subject "aerosol"
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Item Aerosol-cloud Interactions from Urban, Regional, to Global Scales(2013-07-30) Wang, YuanThe studies in this dissertation aim at advancing our scientific understandings about physical processes involved in the aerosol-cloud-precipitation interaction and quantitatively assessing the impacts of aerosols on the cloud systems with diverse scales over the globe on the basis of the observational data analysis and various modeling studies. Long-term impacts of aerosols on precipitation and lightning over the Pearl River Delta megacity area in China are identified through the analysis of seven-year measurements of precipitation, lightning flashes, and visibility from 2000 to 2006. The cloud resolving - Weather Research and Forecasting (CR-WRF) model with a two- moment bulk microphysical scheme is employed to simulate a mesoscale convective system in the Guangzhou megacity area and to elucidate the effects of aerosols on cloud processes, precipitation, and lightning activity. The responses of hydrometeors and latent heat release to different aerosol loadings reveal the physical mechanism for the precipitation and lightning enhancement in the Guangzhou megacity area, showing more efficient mixed phase processes and intensified convection under the polluted aerosol condition. Sensitivity modeling experiments are performed for maritime warm stratocumulus clouds over the southeast Pacific Ocean to evaluate the microphysical parameterizations for simulations of the aerosol effects in regional and global climate models. The Morrison double-moment bulk microphysical scheme presently implemented in the WRF model is modified by replacing the fixed aerosols in the original bulk scheme with a prognostic double-moment aerosol representation to predict both aerosol number concentration and mass mixing ratio. The impacts of the parameterizations of diffusional growth and autoconversion of cloud droplets and the selection of the embryonic raindrop radius on the performance of the bulk microphysical scheme are also evaluated. The impacts of Asian pollution outflows on the Pacific storm track are assessed utilizing reanalysis data, a hierarchical modeling approach and the multi-scale aerosol- climate modeling frame. Statistical analysis of two sets of reanalysis data suggests a strengthened trend of the storm track intensity over the North Pacific since 1979. The two-month seasonal simulations using a CR-WRF model with a two-moment bulk microphysics are performed to examine the aerosol effects on the Pacific storm track intensity. Subsequently, the anomalies of the diabatic heating rate by the Asian pollution outflow derived from the CR-WRF simulations have been prescribed in the NACR Community Atmosphere Model (CAM5) to provide the aerosol forcing terms. The forced GCM well reproduces an enhancement in the intensity of storm track, compared to the unforced model simulations. Similarly, under the multi-scale aerosol-climate modeling frame, the comparisons of the simulated present day versus pre-industrial climate corresponding to two different aerosol scenarios indicate the increased precipitation and poleward heat transport for the present-day climate reveal invigorated mid-latitude cyclones. The current work illustrates the complexity of the aerosol effects on the cloud systems at the diverse scales with different meteorological conditions. This study also stresses the importance of accurate representation of aerosol forcings in the different types of atmospheric numerical models for future climate projections.Item An inhalation model of acute Q fever in guinea pigs(2009-05-15) Russell-Lodrigue, Kasi ElizabethCoxiella burnetii is an intracellular pathogen that can cause both acute and chronic disease (Q fever) in humans and infects many animals with varying clinical illness and persistence. A guinea pig aerosol-challenge model of acute Q fever was developed using infection with C. burnetii across a 5-log range of challenge doses. Clinical signs included fever, weight loss, respiratory difficulty, and death, with degree and duration of response corresponding to dose of organism delivered. Histopathologic evaluation revealed coalescing panleukocytic bronchointerstitial pneumonia 7 days after a high-dose challenge, resolving to multifocal lymphohistiocytic interstitial pneumonia by 28 days. Clinical and pathologic changes noted in these guinea pigs were comparable to those seen in human acute Q fever, making this an accurate and valuable animal model. This model was used to compare the relative virulence of eight isolates from four different genotypic groups: I (RSA493, RSA334, and RSA270), IV (Q177 and Q173), V (Q212 and Q217), and VI (5J108-111). Guinea pigs infected with group I acute-diseaseassociated isolates had severe respiratory disease, while no to moderate clinical illness was observed in animals given group IV or V chronic-disease-associated isolates. 5J108- 111 appeared avirulent. These data suggest that C. burnetii isolates have a range of disease potentials and support a distinction in strain virulence between established genotypic groups, though isolates within the same genomic group cause similar pathologic responses. Heterologous protection was confirmed by cross vaccination and challenge with RSA493 and Q217. A marked non-specific suppression of lymphoproliferation was noted at 14 and 28 days post infection with RSA493; similar suppression was seen after infection with Q173 and Q212 but not 5J108-111. Proinflammatory cytokines IFN-? and TNF-? were produced during early C. burnetii infection, at which time anti-inflammatory cytokines TGF-? and IL-10 were repressed. A vaccine made from phase I C. burnetii was found to be completely protective against lethal infection in the guinea pig model, while vaccination with killed phase II organisms conferred only partial protection, preventing death and reducing but not precluding fever and respiratory illness. Protective vaccination significantly stimulated cell-mediated immunity and elicited increases in IFN-?, TNF-?, and IL-12p40 mRNA levels.Item Degree of mixing downstream of rectangular bends and design of an inlet for ambient aerosol(Texas A&M University, 2006-04-12) Seo, YoungjinTests were conducted to characterize mixing in a square and a rectangular duct with respect to suitability for single point sampling of contaminants. Several configurations, such as a straight duct with unidirectional flow at the entrance section and straight ducts preceded by mixing elements (a 90?? mitred bend, double 90?? bends in S- and U-type configurations) were tested. For a straight duct of square cross section, the COV of tracer gas concentration at 19 duct diameters downstream of the gas release location is 143% (Center release). COVs of velocity and tracer gas concentration downstream of each mixing element in square duct setups were verified throughout this study. In the case of a rectangular duct with a 3:1 (width to height) aspect ratio, COVs of velocity and tracer gas concentration only downstream of a 90?? mitred bend were verified. Tests were conducted to develop improved inlets for a Battelle bioaerosol sampling system. New inlets have been developed called the All Weather Inlets (AWI), which are designed to prevent entry of precipitation while maintaining aerosol penetration. The AWI has two inlets - one that samples at a flow rate of 780 L/min and the other one that is operated at a flow rate of 90 L/min. The initial version of the AWI-780 L/min unit featured an internal cone, which was removed because the penetration of the AWI-780 without the bottom chamber was higher than that of the Battelle inlet ?? 81% with the cone while 86% without the cone for around 9.5 ??m AD at 2 km/h. The best bug-screen configuration was verified and a cutpoint management process was performed. The inlets were tested with different wind speeds from 2 to 24 km/h to verify the wind sensitivity of those inlets.Item Developing models of aerosol representation to investigate composition, evolution, optical properties, and CCN spectra using measurements of size-resolved hygroscopicity(Texas A&M University, 2006-08-16) Gasparini, RobertoA Differential Mobility Analyzer/Tandem Differential Mobility Analyzer (DMA/TDMA) was used to measure size distributions, hygroscopicity, and volatility during the May 2003 Aerosol Intensive Operational Period at the Central Facility of the Atmospheric Radiation Measurement Southern Great Plains site. Hygroscopic growth factor distributions for particles at eight dry diameters ranging from 0.012 ??m to 0.600 ??m were measured. These measurements, along with backtrajectory clustering, were used to infer aerosol composition and evolution. The hygroscopic growth of the smallest and largest particles analyzed was typically less than that of particles with dry diameters of about 0.100 ??m. Condensation of secondary organic aerosol on nucleation mode particles may be responsible for the minimal growth observed at the smallest sizes. Growth factor distributions of the largest particles typically contained a non-hygroscopic mode believed to be composed of dust. A model was developed to characterize the hygroscopic properties of particles within a size distribution mode through analysis of the fixed-size hygroscopic growth measurements. This model was used to examine three cases in which the sampled aerosol evolved over a period of hours or days. Additionally, size and hygroscopicity information were combined to model the aerosol as a population of multi-component particles. With this model, the aerosol hygroscopic growth factor f(RH), relating the submicron scattering at high RH to that at low RH, is predicted. The f(RH) values predicted when the hygroscopic fraction of the aerosol is assumed to be metastable agree better with measurements than do those predicted under the assumption of crystalline aerosol. Agreement decreases at RH greater than 65%. This multi-component aerosol model is used to derive cloud condensation nuclei (CCN) spectra for comparison with spectra measured directly with two Desert Research Institute (DRI) CCN spectrometers. Among the 1490 pairs of DMA/TDMA-predicted and DRI-measured CCN concentrations at various critical supersaturations from 0.02-1.05%, the sample number-weighted mean R2 value is 0.74. CCN concentrations are slightly overpredicted at both the lowest (0.02-0.04%) and highest (0.80-1.05%) supersaturations measured. Overall, this multi-component aerosol model based on size distributions and size-resolved hygroscopicity yields reasonable predictions of the humidity-dependent optical properties and CCN spectra of the aerosol.Item Development of the Captive Aerosol Growth and Evolution Chamber System(2014-08-28) Antonietti, Carlos GThe Captive Aerosol Growth and Evolution (CAGE) Chamber System is an tool designed to study the evolution of aerosols under conditions identical or similar to those of the surrounding environment. Our motivation was to quantify the sensitivity of particle growth rate to trace gas concentrations, oxidants, other particles, and cloud processing. The main objective was to design a pair of transparent, chemically inert, and rotating chambers capable of withstanding a vacuum reflective of typical cloud-top pressures. Aerosol samples taken from the chambers are directed into a suite of instrumentation to study the physical and chemical properties of the evolving aerosol. The chamber system is mounted on a field-deployable trailer through a rotating frame that tracks the sun. Each chamber consists of a set of three concentric thin film cylinders. On both ends of each chamber are inlets and outlets connected through rotary unions for control of trace gas and particle concentrations in the reactor volumes, which rotate about horizontal axes to extend particle retention time. The cylindrical chamber walls are made of transparent FEP Teflon that is both chemically inert and largely transparent for natural solar radiation that drives photo-oxidation processes. The reactor cylinder end walls are made of a permeable Teflon membrane for gas exchange between the inside of the chamber and pre- conditioned or filtered ambient gas. This continuous gas exchange permits dynamic control of the chamber composition without the particle dilution that would accompany a flow- through design. The gas composition in the chambers can be varied for different experimental objectives. Controlled pressure differentials between the concentric volumes are designed to keep the walls semi-rigid during an experiment, while the outermost wall and high strength metal support frame withstand the vacuum in the chambers relative to surrounding air that becomes quite large during cloud formation cycles. The CAGE system was first deployed during September and October 2012 at the Army Research Laboratory outside of Washington D.C. where basic functionalities were tested and experiments conducted to assess the rate at which bioaerosol properties and viability change in ambient air. Daily experiments lasted up to 7 hours, with both chambers rotating at 1 rpm and the platform rotating to track the sun. Injection of two different aerosol types with nearly monodisperse size distribution was followed by intermittent measurement and collection of those captive particles. The gas exchanged with one chamber was first scrubbed and filtered to provide a baseline for comparison while particle-filtered ambient air was exchanged with the other chamber. Preliminary results indicate that single particle fluorescence spectra vary both over time and with differing gas composition.Item Experimental and numerical studies of aerosol penetration through screens(2009-05-15) Han, Tae WonThis research reports the results of experimental and numerical studies performed to characterize aerosol deposition on four different types of commercially available screens (electroformed-wire, woven-wire, welded-wire, and perforated-sheet) over a wide range of Stokes numbers (Stk ~ 0.08 to 20) and Reynolds numbers (ReC ~ 0.5 to 575). The objective of the present research was to use the results of the study to develop models and data that will allow users to predict aerosol deposition on screens. Three-dimensional Computational Fluid Dynamics (CFD) simulations using Fluent (version 6.1.22), as a tool, were undertaken and thus validating the numerical technique and then the result has been compared with the experimental data. For each type of screen, results showed that beginning at critical value of Stokes number where efficiency increased gradually to its maximum value that was almost asymptotic to the areal solidity. It is shown that data obtained from experimental and numerical studies for one particular type of screen would collapse to a single curve if the collection efficiency is expressed in terms of non-dimensional parameters. Correlations characterizing the aerosol deposition process on different types of screens were developed based on the above methodology. The utility of the developed procedure was demonstrated by considering an arbitrary test case, for a particular condition and reconstructing the efficiency curve for the test case. Further, results of the current study were compared with earlier researchers? models (Landahl and Hermann, 1949; Davies, 1952; Suneja and Lee, 1974; Schweers et al., 1994) developed for aerosol deposition on fibrous filters and discussed. These results suggest that the aerosol collection characteristic on different models is different and depends on the nature of the manufacturing process for a typical model (wire or fiber). Finally, the pressure coefficient (Cp) for flow across the screen can be expressed as a function of the Reynolds number (ReC,f) and the fraction of open area (fOA). Correlations expressing the actual relationships were evolved. Additionally, a model was developed to relate pressure coefficient in terms of correction factor (OAfg) and Reynolds number.Item Experimental and theoretical investigation of nucleation and growth of atmospheric aerosols(2009-05-15) Zhao, JunAerosol particles have profound impacts on human health, atmospheric radiation, and cloud microphysics and these impacts are strongly dependent on particle sizes. However, formation and growth of atmospheric particles are currently not well understood. In this work, laboratory and theoretical studies have been performed to investigate the formation and growth of atmospheric particles. The first two parts of the dissertation are a laboratory investigation of new particle formation and growth, and a theoretical study of atmospheric molecular complexes and clusters. The nucleation rate was considerably enhanced in the presence of cis-pinonic acid and ammonia. The composition of the critical cluster was estimated from the dependence of the nucleation rate on the precursor concentration and the time evolution of the clusters was then simulated using molecular dynamic simulations. Results from quantum chemical calculations and quantum theory of atoms in molecules (QTAIM) reveal that formation of strong hydrogen bonding between an organic acid and sulfuric acid is likely responsible for a reduction of the nucleation barrier by modifying the hydrophobic properties of the organic acid and allowing further addition of hydrophilic species (e.g., H2SO4, H2O, and possibly NH3) to the hydrophilic side of the clusters. This promotes growth of the nascent cluster to overcome the nucleation barrier and thus enhances the nucleation in the atmosphere. The last part of this dissertation is the laboratory investigation of heterogeneous interactions of atmospheric carbonyls with sulfuric acid. Direct measurement has been performed to investigate the heterogeneous uptake of atmospheric carbonyls on sulfuric acid. Important parameters have been obtained from the time-dependent or timeindependent uptake profiles. The results indicated that the acid-catalyzed reactions of larger aldehydes (e.g. octanal and 2, 4-hexadienal) in sulfuric acid solution were attributed to aldol condensation in high acidity. However such reactions do not contribute much to secondary organic aerosol (SOA) formation due to the low acidity under tropospheric conditions. On the other hand, heterogeneous reactions of light dicarbonyl such as methylglyoxal likely contribute to SOA formation in slightly acidic media. The reactions of methylglyoxal in the atmospheric aerosol-phase involve hydration and subsequent polymerization, which are dependent on the hygroscopicity, rather than the acidity of the aerosols.Item High Flash-point Fluid Flow System Aerosol Flammability Study and Combustion Mechanism Analysis(2013-12-02) Huang, Szu-YingThe existence of flammable aerosols creates fire and explosion hazards in the process industry. Due to the operation condition of high pressure circumstances, heat transfer fluids tend to form aerosols when accidental leaking occurs on pipelines or storage vessels. An aerosol system is a complicated reactive system; there are neither systematic flammability data similar to the case with pure gases, nor clearly described ignition-to-combustion process of a droplet-air mixture system. The flammable regions of three main, widely-used commercial heat transfer fluids: Paratherm NF (P-NF); Dowtherm-600 (D-600); and Plate Heat Exchange Fluid (PHE), were analyzed by electro-spray generation with laser diffraction particle analysis method. The aerosol ignition behavior depends on the droplet size and concentration of the aerosol. From the adjustment of differently applied electro-spray voltages (7-10 kV) and various liquid feeding rates, a flammable condition distribution was obtained by comparison of droplet size and concentration. All of the fundamental study results are to be applied to practical cases with fire hazards analysis, pressurized liquid handling, and mitigation system design once there is a better understanding of aerosols formed by high-flash point materials. On the other hand, the process of combustion from initial stage to global flame formation was simulated with COMSOL-multi-physics in terms of heat transfer, droplet evaporation, and fluid dynamics of liquid-air interaction. The local temperature change through time, as an indicator of luminous flame appearance, was analyzed to describe the flame development and ignition delay time of aerosols. We have conducted a series of simulation regarding physical formula in description of this combustion process, and will conclude with how temperature distribution influenced the appearance of luminous flames, which was the symbol of successful ignition of aerosol. The mitigation implementing timing and location can be characterized with further understanding of this combustion process. The potential application of the ignition delay will be beneficial to the mitigation timing and detector sensor setting of facilities to prevent aerosol cloud fires. Finally, the scientific method of aerosol flammability study was discussed for its potential impacts on experimental results. A modeling point of view was introduced, with the analysis of electric field application on fuel droplets, and the related fundamental study of the ignition phenomenon on aerosol system. Existing charges from electrospray is beneficial for the monodispersity and control of aerosols for fundamental study. However, the additional charges accumulated on the droplet surfaces are likely to have impacts on flammability due to the excess energy they applied to the aerosols system and droplet-droplet distraction or turbulences. This is a re-visit of aerosol flammability study method, with a conclusion that charges did have positive impact on droplets? ignition concentration range with a balancing effect on turbulence increase to reduce the ignition chance.Item Investigation of the aerosol-cloud interaction using the WRF framework(2009-05-15) Li, GuohuiIn this dissertation, a two-moment bulk microphysical scheme with aerosol effects is developed and implemented into the Weather Research and Forecasting (WRF) model to investigate the aerosol-cloud interaction. Sensitivities of cloud properties to the representation of aerosol size distributions are first evaluated using a simple box model and a cloud resolving model with a detailed spectral-bin microphysics, indicating that the three-moment method generally exhibits better performance in modeling cloud properties than the two-moment method against the sectional approach. A convective cloud event occurring on August 24, 2000 in Houston, Texas is investigated using the WRF model, and the simulation results are qualitatively in agreement with the measurements. Simulations with various aerosol profiles demonstrate that the response of precipitation to the increase of aerosol concentrations is non-monotonic. The maximal cloud cover, core updraft, and maximal vertical velocity exhibit similar responses as precipitation. The WRF model with the two-moment microphysical scheme successfully simulates the development of a squall line that occurred in the south plains of the U.S. Model experiments varying aerosol concentrations from the clean background case to the polluted continental case show that the aerosol concentrations insignificantly influence the rainfall pattern/distribution, but can remarkably alter the precipitation intensity. The WRF experiment with polluted aerosols predicts 12.8% more precipitation than that with clean aerosols, as well as more intensive rainfall locally. Using the monthly mean cloudiness from the International Satellite Cloud Climatology Project (ISCCP), a trend of increasing deep convective clouds over the north Pacific in winter from 1984 to 2005 is detected. Additionally, through analyzing the results from the Global Precipitation Climatology Project (GPCP) version 2, we also show a trend of increasing wintertime precipitation over the north Pacific from 1984 to 2005. Simulations with the WRF model reveal that the increased deep convective clouds and precipitation are reproduced when accounting for the aerosol effect from the increasing Asian pollution outflow.Item Investigation of the optical and cloud forming properties of pollution, biomass burning, and mineral dust aerosols(Texas A&M University, 2006-08-16) Lee, Yong SeobThis dissertation describes the use of measured aerosol size distributions and size-resolved hygroscopic growth to examine the physical and chemical properties of several particle classes. The primary objective of this work was to investigate the optical and cloud forming properties of a range of ambient aerosol types measured in a number of different locations. The tool used for most of these analyses is a differential mobility analyzer / tandem differential mobility analyzer (DMA / TDMA) system developed in our research group. To collect the data described in two of the chapters of this dissertation, an aircraft-based version of the DMA / TDMA was deployed to Japan and California. The data described in two other chapters were conveniently collected during a period when the aerosol of interest came to us. The unique aspect of this analysis is the use of these data to isolate the size distributions of distinct aerosol types in order to quantify their optical and cloud forming properties. I used collected data during the Asian Aerosol Characterization Experiment (ACE-Asia) to examine the composition and homogeneity of a complex aerosol generated in the deserts and urban regions of China and other Asian countries. An aircraft-based TDMA was used for the first time during this campaign to examine the size-resolved hygroscopic properties of the aerosol. The Asian Dust Above Monterey (ADAM-2003) study was designed both to evaluate the degree to which models can predict the long-range transport of Asian dust, and to examine the physical and optical properties of that aged dust upon reaching the California coast. Aerosol size distributions and hygroscopic growth were measured in College Station, Texas to investigate the cloud nucleating and optical properties of a biomass burning aerosol generated from fires on the Yucatan Peninsula. Measured aerosol size distributions and size-resolved hygroscopicity and volatility were used to infer critical supersaturation distributions of the distinct particle types that were observed during this period. The predicted cloud condensation nuclei concentrations were used in a cloud model to determine the impact of the different aerosol types on the expected cloud droplet concentration. RH-dependent aerosol extinction coefficients were also calculated.Item Laboratory investigation of chemical and physical properties of soot-containing aerosols(Texas A&M University, 2006-08-16) Zhang, DanSoot particles released from fossil fuel combustion and biomass burning have a large impact on the regional/global climate by altering the atmospheric radiative properties and by serving as cloud condensation nuclei (CCN). However, the exact forcing is affected by the mixing of soot with other aerosol constituents, such as sulfuric acid. In this work, experimental studies have been carried out focusing on three integral parts: (1) heterogeneous uptake of sulfuric acid on soot; (2) hygroscopic growth of H2SO4-coated soot aerosols; (3) effect of H2SO4 coating on scattering and extinction properties of soot particles. A low-pressure laminar-flow reactor, coupled to ion driftchemical ionization mass spectrometry (ID-CIMS) detection, is used to study uptake coefficients of H2SO4 on combustion soot. The results suggest that uptake of H2SO4 takes place efficiently on soot particles, representing an important route to convert hydrophobic soot to hydrophilic aerosols. A tandem differential mobility analyzing (TDMA) system is employed to determine the hygroscopicity of freshly generated soot in the presence of H2SO4 coating. It is found that fresh soot particles are highly hydrophobic, while coating of H2SO4 significantly facilitates water uptake on soot even at sub-saturation relative humidities. The results indicate that aged soot particles in the atmosphere can potentially be an efficient source of CCN. Scattering and extinction coefficient measurements of the soot-H2SO4 mixed particles are conducted using a threewavelength Nephelometer and a multi-path extinction cell. Coating of H2SO4 is found to increase the single scattering albedo (SSA) of soot particles which has impact on the aerosol direct radiative effect. Other laboratory techniques such as transmission electron microscopy (TEM) and Fourier transform infrared spectrometry (FTIR) are utilized to examine the morphology and chemical composition of the soot-H2SO4 particles. This work provides critical information concerning the heterogeneous interaction of soot and sulfuric acid, and how their mixing affects the hygroscopic and optical properties of soot. The results will improve our ability to model and assess the soot direct and indirect forcing and hence enhance our understanding of the impact of anthropogenic activities on the climate.Item Laminar Flame Speeds of Nano-Aluminum/Methane Hybrid Mixtures(2014-12-12) Sikes, TravisAn existing flame speed bomb, which uses optical techniques to measure laminar flame speed, was employed to study the fundamental phenomena of flame propagation through a uniformly dispersed aerosol. In a previous thesis by Andrew Vissotski, the groundwork was laid to begin studies of hybrid flames. Beginning from these preliminary findings, the facility was upgraded to disperse dust into the test chamber through a strong burst of gas. This aerosol was then allowed to settle for a minimum of 45 seconds to ensure that the conditions inside the test chamber were quiescent and that the dust was uniformly distributed. Extinction of laser light through the resulting aerosol was measured through the large optical access with a 632.8-nm, 5-mW HeNe laser so that the mass of suspended nano-particles could be determined as a function of time up until combustion has occurred. The particles used in these experiments were aluminum nano-particles with a manufacturer-stated average fundamental particle size of 100 nm. To properly quantify the particle distribution inside of the vessel, a scanning mobility particle sizer was employed to characterize the aluminum, resulting in an average particle size of 446.1 nm. With a calibrated extinction measurement, experimental suspended mass of aluminum was measured up to 90 mg. A hybrid mixture of Al/CH4 was chosen to serve as the combustion medium and to provide a well-characterized parent fuel to measure the contribution of nano-aluminum on combustion. Two series of experiments were performed, both at stoichiometric conditions: one with the mixture in air and the second with the mixture in a 70/30 N2/O2 mix. The results herein show a maximum decrease in flame speed, 5-7% from the neat mixture, when nano-aluminum is introduced. In the 70/30 N2/O2 mixture, the addition of aluminum results in a maximum decrease of 5 cm/s from the neat flame speed of 80.5 cm/s and in the air mixture, a 2 cm/s maximum decrease from 35.3 cm/s. A preliminary spectroscopic analysis was performed but was inconclusive. It was also found that the addition of nanoparticles cause the flame to become unstable faster when compared to the neat mixture of CH4/air.Item Measurement and prediction of aerosol formation for thesafe utilization of industrial fuids(Texas A&M University, 2004-09-30) Krishna, KiranMist or aerosol explosions present a serious hazard to process industries. Heat transfer fluids are widely used in the chemical process industry, are flammable above their flash points, and can cause aerosol explosions. Though the possibility of aerosol explosions has been widely documented, knowledge about their explosive potential is limited. Studying the formation of such aerosols by emulating leaks in process equipment will help define a source term for aerosol dispersions and aid in characterizing their explosion hazards. Analysis of the problem of aerosol explosions reveals three major steps: source term calculations, dispersion modeling, and explosion analysis. The explosion analysis, consisting of ignition and combustion, is largely affected by the droplet size distribution of the dispersed aerosol. The droplet size distribution of the dispersed aerosol is a function of the droplet size distribution of the aerosol formed from the leak. Existing methods of dealing with the problem of aerosol explosions are limited to enhancing the dispersion to prevent flammable concentrations and use of explosion suppression mechanisms. Insufficient data and theory on the flammability limits of aerosols renders such method speculative at best. Preventing the formation of aerosol upon leaking will provide an inherently safer solution to the problem. The research involves the non-intrusive measurement of heat transfer fluid aerosol sprays using a Malvern Diffraction Particle Analyzer. The aerosol is generated by plain orifice atomization to simulate the formation and dispersion of heat transfer fluid aerosols through leaks in process equipment. Predictive correlations relating aerosol droplet sizes to bulk liquid pressures, temperatures, thermal and fluid properties, leak sizes, and ambient conditions are presented. These correlations will be used to predict the conditions under which leaks will result in the formation of aerosols and will ultimately help in estimating the explosion hazards of heat transfer fluid aerosols. Heat transfer fluid selection can be based on liquids that are less likely to form aerosols. Design criteria also can incorporate the data to arrive at operating conditions that are less likely to produce aerosols. The goal is to provide information that will reduce the hazards of aerosol explosions thereby improving safety in process industries.