Browsing by Subject "acidizing"
Now showing 1 - 7 of 7
Results Per Page
Sort Options
Item A model for matrix acidizing of long horizontal well in carbonate reservoirs(2009-06-02) Mishra, VarunHorizontal wells are drilled to achieve improved reservoir coverage, high production rates, and to overcome water coning problems, etc. Many of these wells often produce at rates much below the expected production rates. Low productivity of horizontal wells is attributed to various factors such as drilling induced formation damage, high completion skins, and variable formation properties along the length of the wellbore as in the case of heterogeneous carbonate reservoirs. Matrix acidizing is used to overcome the formation damage by injecting the acid into the carbonate rock to improve well performance. Designing the matrix acidizing treatments for horizontal wells is a challenging task because of the complex process. The estimation of acid distribution along wellbore is required to analyze that the zones needing stimulation are receiving enough acid. It is even more important in cases where the reservoir properties are varying along the length of the wellbore. A model is developed in this study to simulate the placement of injected acid in a long horizontal well and to predict the subsequent effect of the acid in creating wormholes, overcoming damage effects, and stimulating productivity. The model tracks the interface between the acid and the completion fluid in the wellbore, models transient flow in the reservoir during acid injection, considers frictional effects in the tubulars, and predicts the depth of penetration of acid as a function of the acid volume and injection rate at all locations along the completion. A computer program is developed implementing the developed model. The program is used to simulate hypothetical examples of acid placement in a long horizontal section. A real field example of using the model to history match actual treatment data from a North Sea chalk well is demonstrated. The model will help to optimize acid stimulation in horizontal wells.Item A Novel Model for Fracture Acidizing with Important Thermal Effects(2013-12-05) Lyons, JohnFracture acidizing is a well stimulation technique used to improve the productivity of low-permeability reservoirs, and to bypass deep formation damage. The reaction of injected acid with the rock matrix forms etched channels (that depend on injection rate, mass transport properties, formation mineralogy, reaction chemistry of the acid, and temperature) through which oil and gas can then flow upon production. The use of a model that can effectively describe fracture acidizing is an essential step in designing an efficient and economical treatment. Several studies have been conducted on modeling fracture acidizing, however, most of these studies have not accounted for the effect of variation in acid temperature (by heat exchange with the formation and the heat generated by acid reaction with the rock) on reaction rate and mass transfer of acid inside the fracture. In this study, a new fracture acidizing model is presented that uses the lattice Boltzmann method for fluid transport and takes into account these temperature effects. The lattice Boltzmann method incorporates both accurate hydrodynamics and reaction kinetics at the solid-liquid interface. This method is also well known for its capability to handle re- active transport in complex geometries. This enables the method to model realistic fracture shapes, on a pore-scale level, and predict the shape of the fracture after acidizing. Results of carbonate fracture dissolution with and without the thermal effects are presented. It is found that including thermal effects alters the predicted shape of the fracture after acidizing.Item Chemical Additive Selection in Matrix Acidizing(2011-05-09) Weidner, Jason 1981-This work proposes to survey new chemical knowledge, developed since 1984, on fluid additives used in matrix stimulation treatments of carbonate and sandstone petroleum reservoirs and describes one method of organizing this new knowledge in a software program using the Visual Basic for Applications programming language. While matrix stimulation treatments have been used in the petroleum industry for over 100 years, the last major review of the technical literature addressing this process occurred in 1984. Currently though, the petroleum industry better understands formation damage; uses different and more chemical additives in matrix stimulation treatments; and understands how some additives interact with one another affecting well performance. As a result, a new and thorough review of the literature regarding chemical additive choices for matrix stimulation treatments will help practicing engineers achieve better results worldwide. Moreover, organizing this chemical knowledge in a software program using VBA allows an engineer to access the information through Microsoft's widely available spreadsheet program, Microsoft Excel.Item Effects of Acid Additives on Spent Acid Flowback through Carbonate Cores(2012-07-16) Nasir, Ehsaan AhmadMatrix acidizing is a well stimulation technique used to remove formation damage in the near wellbore region. But it comes with an associated set of challenges such as corrosion of the tubulars and iron precipitation in the formation. To counter these challenges, different chemicals, or additives, are added to the acid solution such as corrosion inhibitors and iron control agents. These additives may change the relative permeability of the spent acid, and formation wettability, and may either hinder or improve spent acid clean-up. Such effects of additives on the spent acid clean-up have not been documented. The aim of this research effort was to document the aforementioned change in the spent acid concentration (by using one additive at a time) before and after gas flowback. This was achieved by acidizing cores and creating wormholes halfway through them, then CT scanning them to observe the spent acid region. Later on, gas was flown through the core opposite to the direction of acid injection for 2 hours, and another CT scan was taken. The difference between the two CT scans was documented. Using a different additive each time, a series of such CT scans was obtained to develop an idea about whether the said additive was beneficial or detrimental to spent acid clean-up. It was found that the corrosion inhibitor FA-CI performed the best in terms of spent acid recovery after gas flowback for both Indiana Limestone and Texas Cream Chalk cores. Moreover, the corrosion inhibitor MI-CI was the worst for Indiana Limestone and the non-emulsifying agent M-NEA the worst for Texas Cream Chalk for spent acid recovery after gas flowback.Item Experimental High Velocity Acid Jetting in Limestone Carbonates(2014-04-30) Holland, ChristopherAcid jetting is a well stimulation technique that is used in carbonate reservoirs. It typically involves injecting acid down hole at high flow rates through small orifices which cause high velocities of acid to strike the borehole wall. The combination of high kinetic energy and chemical reaction of the acid removes drilling mud filter cake from the borehole wall and produces long conductive channels, called wormholes, into the formation, therefore improving well performance. Studies have shown that injecting fluid down hole at high velocities can mitigate damage to wellbore caused by drilling mud filter cake. Both water and acid have shown positive results in such cases. However, there are no laboratory results on how high velocity acid impacts the borehole wall and the formation of wormholes. The purpose of this study is to investigate how the high velocity acid affects the acidizing treatments. The experiments are conducted on 4? diameter by 16? length Indiana limestone cores with acid injected at the velocity of 106 ft/s, 150 ft/s, and 200 ft/s. The experiments are conducted with a constant pressure differential across the core. 15%wt Hydrochloric acid is injected at room temperature at various flux rates. The results show that the higher the velocity of jetted acid, the further it penetrates into the formation. The 200 ft/s acid penetrates furthest into the core, thus potentially lowering the skin factor the greatest. A large cavity is formed into the core from the high velocity acid. This large cavity creates a pathway for acid to divert into the core to create wormholes. Acid jetting cannot be directly compared with matrix acidizing because of the formation of these large cavities. The Buijse-Glasbergen model that is used to predict the formation of wormholes does not accurately match the acid jetting data due to the formation of these large cavities, so the optimum flux and pore volume to breakthrough cannot be accurately determined.Item Further Investigation of Fluoboric Acid in Sandstone Acidizing Using ^(11)B and ^(19)F NMR(2014-05-01) Pituckchon, ArpajitAlthough fluoboric acid (HBF_(4)) has long been known as one of the low-damaging acid treatments for clayey sandstone formations, little is known of its chemistry which could explain the mixed results of fluoboric acid in actual field application. A better understanding of its limitations would contribute to an improved success rate in HBF_(4) stimulation application. The unique advantages of this acid system are the ability to reach deeper into formation to address damage at extended radius before spending, owing to its slow hydrolytic reaction to produce HF, as well as the stabilization and desensitization of undissolved fines with borosilicate. A more comprehensive understanding of how the chemistry of fluoboric acid and its reaction products affect silica and aluminosilicates is crucial to the design and optimization of fluoboric acidizing treatment. Through a novel application of ^(11)B and ^(19)F Solution State High Field Nuclear Magnetic Resonance (NMR) spectroscopy, chemical complexes involved in the reaction were defined. Various other experimental techniques were also employed in studies on the ability of hydrolyzed fluoboric acid to react with common clays found in sandstone at room and elevated temperatures, as well as coreflooding to investigate clay migration development. Analyzing fresh and spent acid with inductively coupled plasma (ICP) and ^(11)B and ^(19)F NMR helps identify reaction products and their distribution. A set of 12-3 mud acid experiments was done in parallel to serve as a reference to 3%- equivalent-HF fluoboric acid in aqueous-HCl solution. NMR results show complex mixtures of fluoborate species from HBF_(4) hydrolysis and products from HF-aluminosilicates reaction. The fresh HB_(F4) hydrolysis study at room temperature has confirmed retarded HF generation with presence of BF_(4)- and BF_(3)(OH)- and absence of BF_(2)(OH)_(2)- or BF(OH)_(3)- species . The effect of temperature on HBF4 reaction has also been studied to validate functionality of acid at 75?F and 200?F. A series of lab dynamic flow testing in Berea sandstone corroborates conclusions from lab experiments by showing decrease in permeability when treating Berea sandstone cores with HBF_(4) at 200?F. Fluoboric acid treatment is therefore not suitable for formations with approximate temperature of 200?F.Item Modeling and Optimization of Matrix Acidizing in Horizontal Wells in Carbonate Reservoirs(2013-05-07) Tran, HauIn this study, the optimum conditions for wormhole propagation in horizontal well carbonate acidizing was investigated numerically using a horizontal well acidizing simulator. The factors that affect the optimum conditions are rock mineralogy, acid concentration, temperature and acid flux in the formation. The work concentrated on the investigation of the acid flux. Analytical equations for injection rate schedule for different wormhole models. In carbonate acidizing, the existence of the optimum injection rate for wormhole propagation has been confirmed by many researchers for highly reactive acid/rock systems in linear core-flood experiments. There is, however, no reliable technique to translate the laboratory results to the field applications. It has also been observed that for radial flow regime in field acidizing treatments, there is no single value of acid injection rate for the optimum wormhole propagation. In addition, the optimum conditions are more difficult to achieve in matrix acidizing long horizontal wells. Therefore, the most efficient acid stimulation is only achieved with continuously increasing acid injection rates to always maintain the wormhole generation at the tip of the wormhole at its optimum conditions. Examples of acid treatments with the increasing rate schedules were compared to those of the single optimum injection rate and the maximum allowable rate. The comparison study showed that the increasing rate treatments had the longest wormhole penetration and, therefore, the least negative skin factor for the same amount of acid injected into the formations. A parametric study was conducted for the parameters that have the most significant effects on the wormhole propagation conditions such as injected acid volume, horizontal well length, acid concentration, and reservoir heterogeneity. The results showed that the optimum injection rate per unit length increases with increasing injected acid volume. And it was constant for scenarios with different lateral lengths for a given system of rock/ acid and injected volume. The study also indicated that for higher acid concentration the optimum injection rate was lower. It does exist for heterogeneous permeability formations. Field treatment data for horizontal wells in Middle East carbonate reservoirs were also analyzed for the validation of the numerical acidizing simulator.