Browsing by Subject "Water vapor"
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Item Fatigue Resistance of Asphalt Mixtures Affected by Water Vapor Movement(2013-11-08) Tong, YunweiThis dissertation has two key objectives: the first objective is to develop a method of predicting and quantifying the amount of water that can enter into a pavement system by vapor transport; the second objective is to identify to which extent the fatigue crack growth of pavement would result from such moisture accumulation. To fulfill these two objectives, a diffusion model was first established to illustrate the wetting process of the surface asphalt layer due to the vapor migration from subgrade soil into the upper layer. Secondly, in order to quantify the degree of moisture damage induced by water vapor diffusion, fine aggregate mixture specimens were fabricated and conditioned at different levels of relative humidity in closed vacuum desiccators that allows little temperature fluctuation. Moreover, the moisture conditioned specimens were tested using a newly developed repeated direct tension test method to evaluate the fatigue crack growth. The RDT test greatly reduced the stress state complexity within the specimens by evenly distributing stress over the cross section area of the cylindrical specimen. Compared to the previous torsional test, the newly proposed test protocol was more efficient in characterizing the moisture susceptibility of the asphalt mixture. A major finding in this dissertation is that the higher level of RH in as asphalt surface layer will induce significantly higher crack growth rates.Item Synthesis gas production using non-thermal plasma reactors(2014-08) Taylan, Onur; Berberoglu, HalilToday we face the formidable challenge of meeting the fuel needs of a growing population while minimizing the adverse impacts on our environment. Thus, we search for technologies that can provide us with renewable fuels while mitigating the emission of global pollutants. To this end, use of non-thermal plasma processes can offer novel methods for efficiently and effectively converting carbon dioxide and water vapor into synthesis gas for the production of renewable fuels. Particularly, non-thermal plasma technologies offer distinct advantages over conventional methods including lower operating temperatures, reduced need for catalysts and potentially lower manufacturing and operation costs. The non-thermal plasma reactors have been studied for ozone generation, material synthesis, decontamination, thruster for microsatellites, and biomedical applications. This dissertation focuses on producing synthesis gas using a non-thermal, microhollow cathode discharge (MHCD) plasma reactor. The prototype MHCD reactor consisted of a mica plate as a dielectric layer that was in between two aluminum electrodes with a through hole. First, electrical characterization of the reactor was performed in the self-pulsing regime, and the reactor was modeled with an equivalent circuit which consisted of a constant capacitance and a variable, negative differential resistance. The values of the resistor and capacitors were recovered from experimental data, and the introduced circuit model was validated with independent experiments. Experimental data showed that increasing the applied voltage increased the current, self-pulsing frequency and average power consumption of the reactor, while it decreased the peak voltage. Subsequently, carbon dioxide and water vapor balanced with argon as the carrier gas were fed through the hole, and parametric experiments were conducted to investigate the effects of applied voltage (from 2.5 to 4.5 kV), flow rate (from 10 to 800 mL/min), CO₂ mole fraction in influent (from 9.95% to 99.5%), dielectric thickness (from 150 to 450 [mu]m) and discharge hole diameter (from 200 to 515 [mu]m) on the composition of the products, electrical-to-chemical energy conversion efficiency, and CO₂-to-CO conversion yield. Within the investigated parameter ranges, the maximum H2/CO ratio was about 0.14 when H2O and CO₂ were dissociated in different reactors. Additionally, at an applied voltage of 4.5 kV, the maximum yields were about 28.4% for H2 at a residence time of 128 [mu]s and 17.3% for CO at a residence time of 354 [mu]s. Increasing residence time increased the conversion yield, but decreased the energy conversion efficiency. The maximum energy conversion efficiency of about 18.5% was achieved for 99.5% pure CO₂ at a residence time of 6 [mu]s and an applied voltage of 4.5 kV. At the same applied voltage, the maximum efficiency was about 14.8% for saturated CO₂ at a residence time of 12.8 [mu]s. The future work should focus on optimizing the conversion yield and efficiency as well as analyzing the temporal and spatial changes in the gas composition in the plasma reactor.