Browsing by Subject "Photovoltaics"
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Item Colloidal nanocrystals with near-infrared optical properties : synthesis, characterization, and applications(2011-12) Panthani, Matthew George; Korgel, Brian Allan, 1969-; Dodabalapur, Ananth; Chelikowsky, James; Mullins, C. Buddie; Manthiram, ArumugamColloidal nanocrystals with optical properties in the near-infrared (NIR) are of interest for many applications such as photovoltaic (PV) energy conversion, bioimaging, and therapeutics. For PVs and other electronic devices, challenges in using colloidal nanomaterials often deal with the surfaces. Because of the high surface-to-volume ratio of small nanocrystals, surfaces and interfaces play an enhanced role in the properties of nanocrystal films and devices. Organic ligand-capped CuInSe2 (CIS) and Cu(InXGa1-X)Se2 (CIGS) nanocrystals were synthesized and used as the absorber layer in prototype solar cells. By fabricating devices from spray-coated CuInSe nanocrystals under ambient conditions, solar-to-electric power conversion efficiencies as high as 3.1% were achieved. Many treatments of the nanocrystal films were explored. Although some treatments increased the conductivity of the nanocrystal films, the best devices were from untreated CIS films. By modifying the reaction chemistry, quantum-confined CuInSeXS2-X (CISS) nanocrystals were produced. The potential of the CISS nanocrystals for targeted bioimaging was demonstrated via oral delivery to mice and imaging of nanocrystal fluorescence. The size-dependent photoluminescence of Si nanocrystals was measured. Si nanocrystals supported on graphene were characterized by conventional transmission electron microscopy and spherical aberration (Cs)-corrected scanning transmission electron microscopy (STEM). Enhanced imaging contrast and resolution was achieved by using Cs-corrected STEM with a graphene support. In addition, clear imaging of defects and the organic-inorganic interface was enabled by utilizing this technique.Item Coupling photovoltaics and grid-scale energy storage : performance and sitability(2015-05) Stoll, Brady Leigh; Deinert, Mark; Baldick, Ross; Edgar, Thomas; Howell, John; Shi, Li; Webber, MichaelThe Fifth Assessment of the International Panel on Climate Change has called for a four fold increase in the use of low-carbon sources of electricity to help stabilize climate change by mid century. Many people look to solar power systems to help reduce carbon intensity, but cost and variability have been significant obstacles to their widespread deployment. However, the cost of photovoltaics has dropped significantly in recent years, and grid-scale energy storage technologies are available to allow for production of dispatchable electricity from photovoltaics. In particular, compressed-air energy storage is both low-cost and can be built in a wide variety of geologies as well as above ground. I show that coupling large-scale photovoltaic arrays and grid-scale storage allows for dispatchable electricity production at costs that are comparable to other low carbon electricity sources. I examine four load curves: base-load generation, on-peak generation, and averaged load curves for the Electric Reliability Council of Texas (ERCOT) and PJM Independent System Operators. I found that on-peak and ERCOT loads typically required the lowest amount of storage, up to 2000 MWh [subscript e] less than that for base-load generation. However, in some regions, and for some storage amounts, baseload output actually provided the lowest cost of electricity. I also show that such coupled systems could provide base-load electricity for ≤ 0.08/kWh [subscript e] on more than 40% of global land surface, with a capacity factor equivalent to that of the US nuclear fleet. Importantly, this is below the projected cost of electricity from new nuclear power systems. While cost is a major factor, also of importance is where systems of photovoltaics and grid-scale storage would provide the most benefit. Locations expected to provide energy at the lowest cost do not necessarily correspond to load and population centers, where the electricity is most needed. I use multi-criteria decision analysis techniques to perform a global study of the optimal locations for siting these coupled systems to maximize their social benefit. I found that the most ideal locations are generally located in Africa, Iraq, and southeast Asia, as these locations have both high irradiance levels as well as expanding populations and low grid connectivity.Item CuInSe₂ nanowires and earth-abundant nanocrystals for low-cost photovoltaics(2013-05) Steinhagen, Chet Reuben; Korgel, Brian Allan, 1969-Widespread commercialization of photovoltaics (PVs) requires both higher power conversion efficiencies and low-cost, high throughput manufacturing. High efficiencies have been achieved in devices made from materials such as CuIn[subscript x]Ga₁₋[subscript x]Se₂ (CIGS). However, processing of these solar cells still requires high temperature and vacuum, driving up cost. A reduction in manufacturing costs can be achieved by utilizing colloidal nanocrystals. Semiconductor nanocrystals can be dispersed in solvents and deposited via simple and scalable methods under ambient conditions to form the absorber layer in low-cost solar cells. Efficiencies of ~3% have been achieved with CIGS nanocrystal PVs, but this must be improved substantially for commercialization. These devices suffer from poor charge transport in the nanocrystal layer. Here, the synthesis of nanowires and their utilization in solar cells was explored as a way to improve charge transport. CuInSe₂ (CIS) nanowires were synthesized via the solution-liquid-solid method. PV devices were fabricated using the nanowires as the light absorbing layer, and were found to exhibit a measureable power output. Earth-abundant materials were also explored, motivated by the material availability concerns associated with CIGS. Pyrite FeS₂ nanocrystals were synthesized via an arrested precipitation reaction to produce phase-pure particles 15 nm in size. These nanocrystals were spray coated to form the active layer in several different common device architectures. These devices failed to produce any power output. The material was determined to be slightly sulfur deficient, leading to a high carrier concentration and metallic behavior in the thin films, with conductivities measured to be ~5 S/nm. A nanocrystal synthesis of Cu₂ZnSnS₄ (CZTS) was also developed to produce highly dispersible crystalline particles ~11 nm in size. These nanocrystals were spray coated onto glass substrates to form the absorber layer in test PV devices, and an efficiency of 0.23% was achieved without high-temperature or chemical post-processing. Additional studies included the synthesis of CZTS nanorods and their incorporation into functioning solar cells. The selenization of CZTS nanocrystal films was also studied as a way to improve solar cell performance. High temperature annealing in a Se atmosphere was found to produce CZTS(Se) layers, which could be used in working PV devices.Item Electronic materials based on conducting metallopolymers and self-assembly(2014-12) Nguyen, Minh Tu, Ph. D.; Holliday, Bradley J.; Korgel, Brian A.; Rose, Michael J.; Humphrey, Simon M.; Vanden Bout, David A.Conducting metallopolymers (CMPs) have been extensively studied due to their potential for various applications in sensing, catalysis, light-emitting diodes, and energy harvesting and storage. The incorporation of metal centers into conjugated organic polymer backbones not only makes these materials multi-functional, but also changes the properties, such as electroactivity and conductivity. In this work, we aim to take advantage of the direct electronic interaction between metal centers and polymer backbones in these metallopolymers to make novel materials that could be used for photovoltaic and spintronic applications. Furthermore, a fundamental study on the interactive role of transition metals in conducting metallopolymers has been conducted, which could help to provide insights for the rational design of metallopolymers for certain applications. Charge transfer in hybrid photovoltaics is often inhibited by the capping ligands on inorganic semiconductors. To bypass the ligand effect, my study was focused on preparing a conducting metallopolymer, in which metal ions are directly bound to the conjugated organic backbone. These metal ions will serve as nucleation or seed points upon which the inorganic semiconductor can grow directly within the polymer matrix. This fabrication method provides materials with direct bonds between the inorganic semiconductor and the conducting polymer backbone and therefore results in direct electronic communication between the donor and acceptor. With this material, the charge transfer limited by capping ligands could be overcome and can result in highly efficient devices when utilized in solar cells. Besides the efforts to harvest energy form renewable resources, changing the way that we use energy (e.g., in lighting and information storage) could also help to reduce our energy demand. The bistability offered by spin-crossover (SCO) complexes has resulted in sustained research interest due to potential applications in molecular electronics such as memory storage. Interested in making memory devices with a bottom up approach, we have designed and prepared CMPs that are not only conductive but also possess spin-crossover behavior. The novelty of this study lies in the fact that spin-switching could be possibly obtained by changing the oxidation states of metal centers, which could be done at room temperature, offering a new method for spin switching compared to conventional methods for SCO such as in thermal-induced spin transition. To study the charge delocalization and charge transport in CMPs, a series of conducting polymers of Schiff-base ligands and metal complexes have been prepared and characterized. Our successful syntheses of ligand polymers allows for full characterization and direct comparison of these polymers to the corresponding metal-containing polymers, from which the role of the metal centers is elucidated. The effects of conjugation length on electrochemical and spectroscopic properties are also investigated and discussed.Item Enhanced solar absorption in thin film photovoltaic cells via embedded silica-coated silver nanoparticles(2015-12) Aminfard, Sam; Ben-Yakar, Adela; Harrison, Richard KThin-film photovoltaic cells are a promising technology that can harvest solar energy at a low cost. The main drawback of this technology is its low efficiency in comparison to conventional photovoltaics. This deficiency is due to poor absorption of long wavelengths in the solar spectrum. Plasmonic nanostructures can be tuned to resonantly interact with these wavelengths in order to enhance a solar cell’s absorption of these wavelengths and improve its efficiency. Historically, the two key factors limiting the success of plasmonically-enhanced photovoltaics have been parasitic absorption of light by the nanoparticle lost to heating, and recombination of charge carriers at the interface of the nanoparticle and the photovoltaic medium. Here we propose that these deficiencies can be overcome by employing nanospheres with a silver core and silica shell. Through experimentation supported by simulations, this thesis outlines how these plasmonic nanostructures can be applied to significantly improve the performance thin-film solar cells through experimentation supported by simulations. The plasmonic enhancement of photovoltaic devices can be studied and optimized computationally; however, highly uniform nanoparticles are necessary to validate these simulations.. The colloidal synthesis of plasmonic nanoparticles can achieve this at a low cost. We present several methods for the synthesis of silver nanoparticles with diameter of 5 to 50 nm and compare the monodispersity and yield of the colloids that they produce. These colloids are then adapted to synthesis processes enabling the formation of silica shells of 2 to 20 nm onto the silver cores. To facilitate the integration of silver-core, silica-shell nanoparticles into semiconductor thin films, we also develop procedures to deposit these nanoparticles onto silicon substrates with precisely-controlled inter-particle spacing. Finally, we experimentally integrate silver-core, silica shell nanoparticles into sub-micron layers of silicon. Absorption measurements reveal that integration of these nanoparticles can nearly double the amount of light absorbed by the silicon. The absorption spectra indicate the strong presence of interference effects within the thin films, which we account for in our simulations. We use the simulations to show how parasitic absorption by the nanoparticle only accounts for a small percentage of the absorption gains that we measure. Therefore, most of the optical absorption happens within the silicon, and would potentially improve the efficiency of a silicon solar cell.Item Hybrid Photovolvoltaic Devices Based on Nanocrystals and Conducting Metallopolymers Using the Seeded Growth Method(2011-08) Huynh, Uyen Nguyen Phuong; Holliday, Bradley J.; Jones, Richard A.Described herein are two projects focusing on developing and investigating two types of nanoparticles (NPs) grown by the seeded growth method from a conducting metallopolymer for photovoltaic (PV) applications. Core/shell CdS/ZnS NPs are proven to resist the photo-oxidation of PV devices, while CuInxGa(1-x)Se2 (CIGS) NPs are expected to optimize the efficiency of PV devices.Item Low cost processing of CuInSe2 nanocrystals for photovoltaic devices(2015-05) Stolle, Carl Jackson; Korgel, Brian Allan, 1969-; Mullins, Charles B; Manthiram, Arumugam; Vanden Bout, David A; Markert, John TSemiconductor nanocrystal-based photovoltaics are an interesting new technology with the potential to achieve high efficiencies at low cost. CuInSe2 nanocrystals have been synthesized in solution using arrested precipitation and dispersed in solvent to form a “solar ink”. The inks have been deposited under ambient conditions to fabricate photovoltaic devices with efficiency up to 3%. Despite the low cost spray coating deposition technique, device efficiencies remain too low for commercialization. Higher efficiencies up to 7% have been achieved using a high temperature selenization process, but this process is too expensive. New nanocrystal film treatment processes are necessary which can improve the device efficiency at low cost. To this end, CuInSe2 nanocrystals were synthesized using a diphenyl phosphine:Se precursor which allows for precise control over the nanocrystal size. The size is controlled by changing the temperature of the reaction. The smallest size nanocrystals demonstrated extremely high device open circuit voltage. Ligand exchange procedures were used to replace the insulating oleylamine capping ligand used during synthesis with more conductive halide ions or inorganic chalcogenidometallate cluster (ChaM) ligands. These ligands led to improved charge transport in the nanocrystal films. A high-intensity pulsed light processing technique known as photonic curing was used which allows for high temperature sintering of nanocrystal films on temperature-sensitive substrates. High energy pulses cause the nanocrystals to sinter into large grains, primarily through melting and resolidification. The choice of metal back contact has a dramatic effect on the final film morphology, with Au and MoSe2 back contacts providing much better adhesion with the CuInSe2 than Mo back contacts. Nanocrystal sintering without melting can be achieved by replacing the oleylamine ligands with ChaM ligands prior to photonic curing. Low energy photonic curing pulses vaporize the oleylamine ligands without inducing sintering or grain growth. This greatly improved nanocrystal coupling and interparticle charge transport. Multiexcitons were successfully extracted from these nanocrystal films and external quantum efficiencies over 100% were observed. Transient absorption spectroscopy was used to study the multiexciton generation process in CuInSe2 nanocrystal films and colloidal suspensions. The multiexciton generation efficiency, threshold, and Auger lifetimes for CuInSe2 compare well with other nanocrystal materials.Item Mechanisms and applications of near-field and far-field enhancement using plasmonic nanoparticles(2012-12) Harrison, Richard K., 1982-; Ben-Yakar, AdelaThe resonant interaction of light with metal nanoparticles can result in extraordinary optical effects in both the near and far fields. Plasmonics, the study of this interaction, has the potential to enhance performance in a wide range of applications, including sensing, photovoltaics, photocatalysis, biomedical imaging, diagnostics, and treatment. However, the mechanisms of plasmonic enhancement often remain poorly understood, limiting the design and effectiveness of plasmonics for advanced applications. This dissertation focuses on evaluating the mechanisms of plasmonic enhancement and distinguishing between near and far field effects using simulations and experimental results. Thorough characterization of metal nanoparticle colloids shows that electromagnetic simulations can be used to accurately predict the optical response of nanoparticles only if the true shapes and size distributions are taken into account. By coupling these optical interaction calculations with heat transfer models, experimental limits for the maximum optical power before nanoparticle melting can be found. These limits are important for plasmonic multiphoton luminescence imaging applications. Subsequently, we demonstrate ultrafast laser plasmonic nanoablation of silicon substrates using gold nanorods to identify the near-field enhancement and mechanism of plasmon-assisted ablation. The experimentally observed shape of the ablation region and reduction of the ablation threshold are compared with simulations to show the importance of the enhanced electromagnetic fields in near-field nanoablation with plasmonic nanoparticles. The targeted use of plasmonic nanoparticles requires narrow size distribution colloids, because wide size distributions result in a blurring and weakening of the optical response. A new synthesis method is presented for the seeded-growth of nearly monodisperse metal nanoparticles ranging from 10 to 100 nm in diameter, both with and without dielectric shells of controlled thickness. This method is used to acquire fine control over the position and width of the plasmonic peak response. We also demonstrate self-assembled sub-monolayers of these particles with controllable concentrations, which is ideal for looking at plasmonic effects in surface and layered geometries. Finally, we present results for the spatial distribution of absorption around plasmonic nanoparticles. We introduce field-based definitions for distinguishing near-field and far-field regions and develop a new set of equations to determine the point-by-point enhanced absorption in a medium around a plasmonic nanoparticle. This set of equations is used to study plasmon-enhanced optical absorption for thin-film photovoltaic cells. Plasmonic nanoparticle systems are identified using simulations and proof-of-concept experiments are used to demonstrate the potential of this approach.Item Predicting solar max dc power using a linear regression model(2012-05) Kwon, Youngsung; Grady, W. M.; Surya, SantosoThe increase in the consumption of energy year after year emphasizes the importance of power production by photovoltaic (PV) systems. Despite an increase in the use of PV systems, accurate solar power [kWh] daily harvest predicting data are not readily available. Accurate predicted solar power data is necessary because the data is helpful to designers who need to optimally size a PV panel before installation. Moreover, accurately predicted max dc power can indicate whether the PV panel is operating efficiently and economically or not. This thesis develops an approach to predict max solar power based on a Linear Regression model. The approach, which ia a simple regression was implemented using measured data on a response variable, a max solar power (Pmax), and predictor variables such as Global Horizontal (GH), Plane of Array (PA), Short Circuit Current (Isc), Open Circuit Voltage (Voc), and Panel Temperature (Temp). The statistical results of the linear regression model produced reasonable values which agreed with those of the measured data from the solar panel.Item Remote plasma chemical vapor deposition for high efficiency heterojunction solar cells on low cost, ultra-thin, semiconductor-on-metal substrates(2014-12) Onyegam, Emmanuel U.; Banerjee, Sanjay; Yu, Edward T; Sreenivasan, S.V.; Tutuc, Emanuel; Rao, Rajesh AIn the crystalline Si solar cell industry, there is a push to reduce module cost through a combination of thinner substrates and increased cell efficiency. Achieving solar cells with sub-100 µm substrates cost-effectively is a formidable task because such thin substrates impose stringent handling requirements and thermal budget due to their flexibility, ease of breakage, and low yield. Moreover, as the substrate thickness decreases the surface passivation quality dictates the performance of the cells. Crystalline Si heterojunction (HJ) solar cells based on hydrogenated amorphous silicon (a-Si:H) have attracted significant interest in recent years due to their excellent surface passivation properties, potential for high efficiency, low thermal budget and low cost. HJ cells with ultra-passivated surfaces showing > 700 mV open-circuit voltages (Voc) and > 20% conversion efficiency have been demonstrated. In these cells, it has been identified that high-quality a-Si:H films deposited by a low-damage plasma process is key to achieving such high cell performance. However, the options for low-damage plasma deposition process are limited. The main objectives of this work are to develop a low-plasma damage a-Si:H thin film deposition process based on remote plasma chemical vapor deposition (RPCVD) and to demonstrate high efficiency HJ solar cells on bulk substrates as well as on ultra-thin silicon and germanium substrates obtained by a novel, low-cost semiconductor-on-metal (SOM) technology. This manuscript presents a detailed description of the RPCVD system and the process leading to the realization of high quality a-Si:H thin films and high efficiency HJ solar cells. First, p-type a-Si:H thin films are developed and optimized, then HJ solar cells are subsequently fabricated on bulk and ultra-thin Si and Ge SOM substrates without intrinsic a-Si:H passivation. Single HJ cells on ~ 500 µm bulk Si and ~25 µm ultra-thin substrates exhibited conversion efficiencies of η = 16% (Voc = 615 mV, Jsc = 34 mA/cm2, and FF = 77%) and η = 11.2% (Voc = 605 mV, Jsc = 29.6 mA/cm2, and FF = 62.8%), respectively. The performance of the ~25 µm cell was further improved to η = 13.4% (Voc = 645 mV, Jsc = 31.4 mA/cm2, and FF = 66.2%) by implementing the dual HJ architecture without front side i-layer passivation. For single HJ cells based on Ge substrates, the results were η = 1.78 % (Voc = 148 mV, Jsc = 35.1 mA/cm2, and FF = 1.78%) on ~500 µm bulk Ge, compared to η =5.3% (Voc = 203 mV, Jsc = 44.7 mA/cm2, and FF = 5.28%) on ~ 50 µm Ge SOM substrates. Respectively, the results obtained on ultra-thin SOM substrates are among the highest reported in literature for based on comparable architecture and substrate thickness. In order to achieve improved cell performance, dual HJ cells with i-layer passivation of both surfaces were fabricated. First, optimized RPCVD-based i-layer films were developed by varying the deposition temperature and H2 dilution ratio (R). It was found that excellent surface passivation on planar substrates with as-deposited minority carrier lifetimes > 1 ms is achievable by using deposition temperature of 200 ºC and moderate dilution ratio 0.5 ≤ R ≤ 1, even without the more rigorous RCA pre-cleaning process typically used in literature for achieving comparable results. Subsequently, dual HJ solar cells with i-layer films were demonstrated on planar and textured bulk Si substrates showing improved conversion efficiencies of η = 17.3% (Voc = 664 mV, Jsc = 34.34 mA/cm2 and FF = 76%) and η = 19.4% (Voc = 643 mV, Jsc = 38.99 mA/cm2, and FF = 77.5%), respectively.Item Synthesis and characterization of electronic materials for photovoltaic applications(2010-05) Mejia, Michelle Leann; Holliday, Bradley J.; Cowley, Alan H.; Crooks, Richard M.; Dodabalapur, Ananth; Jones, Richard A.Electronic materials are of great interest for use in photovoltaics, sensors, light-emitting diodes, and molecular electronics. Hybrid Inorganic/Organic materials have been studied for device application due to their unique electronic properties. These properties result from the formation of bulk heterojunctions between inorganic (n-type) and organic (p-type) materials. However, due to incomplete pathways for charge transport and poor interfaces between materials, charge trapping and exciton recombination is often high. In an effort to alleviate these problems, we have developed an approach to fabricate bulk heterojunction materials via a seeded growth process. Electropolymerizable Schiff base complexes have been designed, synthesized, and utilized as precursors for conducting metallopolymers. The embedded metal centers are used as seed points for direct growth of size-controllable semiconductor nanoparticles within the polymer film leading to direct electronic communication between the two materials. The synthesis of CdS, CdSe, Ga₂S₃, CuInS₂, CuInSe₂, CuGaS₂, CuGaSe₂, CuGa[subscript x]In[subscript x]-₁S₂, and CuGa[subscript x]In[subscript x]-₁Se₂ has been seen through TEM and EDX. Devices have been fabricated and current studies have focused on the photovoltaic characterization of these materials which have a PCE of 0.11%. As a second but closely related area, polymers have also been studied as organic semiconductors for device applications. However they are hard to process from solution and their polymeric structure can vary. Both of these problems can be solved by using well-defined solution processable oligomers. Thiophene oligomers have been synthesized and characterized through Single Crystal X-Ray Crystallography, Four Point Probe Conductivity, and Powder Diffraction. These oligomers have a well-defined structure and are solution processable from a variety of solvents which can then be used as models to predict and study the properties of polythiophene.Item To conserve or consume : behavior change in residential solar PV owners(2011-12) McAndrews, Kristine Lee; Rai, Varun; Groat, Charles G.A survey of residential solar photovoltaic (PV) adopters in Texas was administered and the results are presented and discussed. A 40% response rate was achieved and 365 complete responses were received. In addition to demographics, the survey uncovered aspects related to the decision-making process, information search, financial attractiveness of PV, and post-installation experience. Peer-effects did not have a large influence on the adoption of residential PV in Texas, but the potential for increasing the number of communication/information channels to increase the adoption rate of PV exists. Adopters experienced little uncertainty at the time of PV installation because sufficient dependable information was available during the search process. Overall, they are satisfied with PV. Contextual factors, such as income and the ability to purchase a PV system rather than lease one, influence behavior. Those who decreased electricity consumption post-adoption were more motivated to adopt by environmental concern and a general interest in energy than those who increased electricity consumption post-adoption. Those who experienced behavior changes also experienced an increase in awareness of electricity use post-adoption, while those who did not experience a behavior change reported no change in awareness post-adoption. Change in awareness of electricity use is less dependent on the attitudinal and contextual factors, such as environmental concern, motivation for adoption, age, and income, that influence consumption change. The potential for further analysis of the survey results is great and will likely yield additional conclusions about the consequences of the adoption of PV. Coupling the survey results with historical electricity bill data will yield stronger conclusions about behavior change. Surveying geographical areas outside of Texas is recommended.Item Zero to sixty hertz : electrifying the transportation sector and enhancing the reliability of the bulk power system(2015-08) Legatt, Michael Elazar; Baldick, Ross; Webber, Michael EA revolution is underway in the energy sector. Traditional approaches for managing a bulk power system are beginning to give way to a "smart grid" world, in which controllers may have bidirectional communications, with engaged users. At the same time a second transformation has been underway and growing in strength, namely the transition from petroleum as a transportation fuel source towards natural gas for large fleet vehicles, and electricity for consumer vehicles. This thesis focuses primarily on the synergy between the "smart grid" and vehicle electrification transitions. Moving the transportation sector to electricity as a fuel source, at least in Texas, has a myriad of benefits: Charging an electric vehicle without significant growth in renewable or lower-emitting SOFC technologies leads to very significant (80% per mile, 58% per neighborhood) reductions in CO₂ emissions, as well as significant reductions in NO[subscript X] (41% per mile, 17% per neighborhood), PM₁₀ (73% / 62%), PM₂.₅ and UFPM (62% / 55%). SO[subscript X] levels rose by 37%, but could be mitigated with controlled EV charging strategies. Vehicle charging strategies also significantly improved the neighborhood's total emissions profile. Adding in distributed energy resources, microgrid generation and intelligent charging, when optimally allocated, can further reduce these emissions. Vehicle charging schemes that respond dynamically to distributed renewable generation can even be thought of as having zero emissions due to the continual balance of PV generation and EV load on the low side of the distribution transformer. This thesis argues that there may be additionally significant societal benefits by shifting vehicle transportation to electricity, likely far in excess of what could be achieved by controlling power plant emissions alone. Based on an analysis of the ERCOT region, this shift would be expected to produce significant cost reductions for overall energy, improve health (due primarily to the relocation of UFPM far away from major population centers), and lower societal costs. Further gains can be considered as electric vehicles are significantly more energy efficient than their ICE counterparts. Also, on a larger scale, it’s generally easier to reduce emissions from hundreds of fixed power plants than millions of moving ICE vehicles.