Browsing by Subject "Periodic orbits"
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Item Chaos, quasibound states, and classical periodic orbits in HOCI(2011-05) Barr, Alexander Michael; Reichl, L. E.; Bengtson, Roger D.; Kopp, Sacha; Sitz, Greg O.; Wyatt, Robert E.We study the classical nonlinear dynamics and the quantum vibrational energy eigenstates of the molecule HOCl. The classical vibrational dynamics, at energies below the HO+Cl dissociation energy, contains several saddle-center and period doubling bifurcations. The saddle-center bifurcations are shown to be due to a 2:1, and at higher energies a 3:1, nonlinear resonance between bend and stretch motions in various periodic orbits. The sequence of bifurcations takes the system from nearly integrable at low energies to almost completely chaotic at energies near the HO+Cl dissociation energy. At energies above dissociation we study the chaotic scattering of the Cl atom off the HO dimer. This scattering is governed by a homoclinic tangle formed by the stable and unstable manifolds of a parabolic periodic orbit at infinity. We construct the first three segments of the homoclinic tangle in phase space and use scattering functions to investigate its higher-order structure. For the quantum system we use a discrete variable representation to efficiently calculate the Hamiltonian matrix. We find 365 even and 357 odd parity eigenstates with energies below the dissociation energy. By plotting the eigenstates in configuration space we show that almost every quantum eigenstate can be associated with one or more of the classical periodic orbits. The classical bifurcations that give rise to new periodic orbits are manifest quantum mechanically through the sudden appearance of new classes of eigenstates. Despite the high degree of chaos in the classical dynamics at energies near the dissociation energy most quantum eigenstates remain highly ordered with recognizable nodal patterns. We use R-matrix theory together with a discrete variable representation to calculate quasibound states with energies above the dissociation energy. We find quasibound states with lifetimes ranging over 5 orders of magnitude. Using configuration space plots and Husimi distributions we show that the long-lived quasibound states are supported by unstable periodic orbits in the classical dynamics and medium-lived quasibound states are spread throughout the chaotic region of the classical phase space. Short-lived quasibound states show some similarity to unstable periodic orbits that stretch along the dissociation channel.Item Eigenfunction construction by classical periodic orbits(1998-08) Jan, Ing-Chieh; Sudarshan, E. C. G.In this dissertation, we devise a quantization scheme to construct eigenfunctions by classical periodic orbits in both regular systems as well as chaotic systems. Our method is based on the principle that eigenfunctions can be resolved from a time-dependent wavefunction. This is different from the classical (or EBK) quantization scheme that constructs eigenfunction in the energy-domain. The advantage of our method is that it can be applied to more varieties of systems, including some chaotic systems. Three systems, the simple harmonic oscillator, the x⁴-potential oscillator, and the x²y² quartic-oscillator, are used as examples for our eigenfunction construction. The key to the constructions is a family (or families) of periodic orbits with a newly defined quantization rule, the resolving quantization rule. The eigenspectrum for the x⁴-potential oscillator is also computed. Furthermore, the classical Green's function is used to explain the relation between the resolving quantization rule and the classical quantization rule. This dissertation begins with an introduction in Chapter 1. The semiclassical theory for the eigenfunction construction by periodic orbits is developed in Chapter 2. In Chapter 3 and Chapter 4, eigenfunctions are constructed for the simple harmonic oscillator, the x⁴-potential oscillator, and the x²y² quartic-oscillator. The eigenspectrum for the x⁴-potential oscillator is computed in Chapter 5. Chapter 6 is devoted to discussions including the interpretation of the resolving quantization rule from the classical Green's function, the interpretation of the photoabsorption spectrum for a Rydberg atom in a magnetic field, and the comparison of our method with the EBK quantization scheme. Conclusions are made in Chapter 7.