Browsing by Subject "Isotherm"
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Item Coefficient of isothermal oil compressibility for reservoir fluids by cubic equation-of-state(2006-12) Adepoju, Olaoluwa Opeoluwa; Heinze, Lloyd R.; Siddiqui, ShameemCoefficients of isothermal oil compressibility are usually obtained from reservoir fluid analysis. Reservoir fluid analysis is an expensive and time consuming operation that is not always available when the volumetric properties of reservoir fluids are needed. For this reason correlations have been developed and are being developed for predicting fluid properties including the coefficient of isothermal oil compressibility. This project developed a mathematical model for predicting the coefficient of isothermal oil compressibility based on Peng-Robinson Equation of State (PR EOS). A computer program was developed to predict the coefficient of isothermal compressibility using the developed model. The predicted coefficient of isothermal oil compressibility closely matches the experimentally derived coefficient of isothermal compressibility.Item Ellipsometric and nanogravimetric porosimetry studies of nanostructured, mesoporous electrodes(2009-12) May, Robert Alan; Stevenson, Keith J.; Crooks, Richard M.; Barbara, Paul F.; Shih, Chih-Kang; Johnston, Keith P.Nanostructured, porous materials offer great promise for application in areas such as energy storage, photovoltaics, and catalysis. These materials are often difficult to characterize because they are structurally and compositionally inhomogeneous, and disordered with features to small to be resolved by scanning probe techniques such as atomic force microscopy (AFM) and scanning electron microscopy (SEM). These shortcomings require that new techniques be developed that can be applied to real world systems to elucidate how the interplay of material composition and structure alters their performance. Towards this end, the development of a hybrid quartz crystal microbalance/ ellipsometric porosimetry (QCM/EP) technique is being pursued to facilitate the determination of a number of material parameters such as porosity, pore size distribution, and surface area. Additionally, the use of adsorbate probe molecules of varying polarity gives further information about adsorbate-surface interactions and surface chemistry characteristics. Simultaneous acquisition of both mass-based and refractive index based adsorption isotherms fosters mechanistic understanding about the behavior of adsorbates confined in mesopores while at the same time reducing the uncertainty in the analysis of the optical parameters acquired via ellipsometry. To highlight the power of this approach, studies of TiO₂ and TiC, electrode materials as model systems will be presented that have helped us validate measurement and modeling protocols for extracting physical properties.