Browsing by Subject "Gulf of Mexico"
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Item 3-D multichannel seismic reflection study of variable-flux hydrocarbon seeps, continental slope, northern Gulf of Mexico(Texas A&M University, 2004-11-15) Thomas, Ryan DouglasIn the northern Gulf of Mexico, seafloor hydrocarbon fluid and gas seepage is an ubiquitous process on the continental margin. Although seafloor seepage and seep-related features (mud volcanoes, carbonate formation) have been studied for many years, little is known about their mechanisms of formation and the relationship of sub-surface structure to current seep activity. In this study, we examined three seafloor seeps in the Garden Banks and Mississippi Canyon areas using exploration and reprocessed 3D multi-channel seismic (MCS) data augmented with side-scan sonar (Garden Banks site) to characterize hydrocarbon seep activity and develop an understanding of the processes that led to their formation. Side-scan sonar data provided high resolution coverage of the seafloor while the exploration seismic data were used to image near and deep sub-surface features. Additionally, the 3D amplitude extraction maps were useful in delineating amplitude anomalies often associated with seep related activity. The reprocessed 3D seismic data were used to map in greater detail near seafloor features and amplitude anomalies. Using remote sensing geophysical data, we were effectively able to map sub-surface features such as salt topography, seep-related faults and geophysical indicators of hydrocarbons and correlate them with seafloor amplitude anomalies and fault traces in order to characterize seep activity level. The southern mud volcano in the Garden Banks site is characterized as an established high flux seep vent owing to signs of active seepage and sediment flows as well as the build-up of hard grounds. The northern mud volcano in the area, with greater hard ground build-up and fewer signs of active seepage represents an established low flux seep vent. In the Mississippi Canyon area, the data suggest that the seep mound can be characterized as a mature high flux vent due to the extensive build-up of hard ground, evidence of gas hydrates and signs of active seepage and sediment flows. The mechanisms of formation are similar between the two study sites. Upwelling salt appears to have fractured the sub-surface leading to the formation of fault induced depressions. Mapping of geophysical indicators of hydrocarbons implies that hydrocarbon migration is occurring along bedding planes to the fault systems underlying the depressions. Here they appear to migrate vertically to the seafloor creating the topographic features and seafloor amplitude anomalies that characterize the seepsItem A 20,000 year flowstone record of Gulf of Mexico sourced moisture in Texas(2016-05) Charlton, Timothy Callison; Banner, Jay L.; Breecker, Dan O.; Musgrove, MaryLynnUnderstanding how future atmospheric warming may affect moisture distribution in the American Southwest is becoming increasingly important. To this end, various paleoclimatic proxies have been used to investigate the range of climatic fluctuations forced by natural processes during past periods of warming. As part of this effort, speleothem-based oxygen isotope records have been used to hypothesize the contribution of either Gulf of Mexico (GoM) or Pacific Ocean sourced moisture since the Last Glacial Maximum (LGM) at cave sites across the Southwest. In this study, a new oxygen isotope time series is developed from a flowstone in central Texas as a means to test this hypothesis. Due to significant age reversals in the U-series chronology, multiple age models were created that use a series of assumptions to exclude questionable age determinations. By comparing these age models, portions of the flowstone that are most likely to produce robust chronologies were identified. The rate, timing, and amplitude of oxygen isotope shifts in all of the age models are consistent with the only other Texas speleothem and one of the few GoM sediment cores that cover the same time period and have an oxygen isotope record. These results support the hypothesis that central Texas had a dominant GoM moisture source since the LGM and that speleothems in the region might record this signal. Furthermore, this study developed a novel workflow that could be applied to other flowstone samples, which would allow for greater spatial coverage of speleothem-based paleoclimate reconstructions when high-quality stalagmite samples are not available.Item Analyzing deep-water near seafloor geology with chirp sonar sub-bottom profiles : Green Canyon, Gulf of Mexico(2006-12) Hernandez, Jaime, 1968-; Fisher, W. L. (William Lawrence), 1932-The study area is located on the continental slope in the Green Canyon deep-water area of the Gulf of Mexico. This area is being investigated by the Bureau of Economic Geology as part of several active gas hydrate studies across the area. The chirp sonar profiles used in my study were collected with an Autonomous Underwater Vehicle (AUV) utilizing a frequency-modulated seismic (sonar) source that emitted a 2 to 8 kHz sweep (chirp) frequency signal (wavelengths less than 2 meters). The recording time is limited to about 50 milliseconds, with time zero occurring at the altitude of the AUV about 50 meters above the seafloor. The signal images to about 40 meters below the seafloor, and profiles are as long as 5 km. An interpretation of deep-water, near sea-floor geology has been conducted using both chirp sonar profiles and multibeam bathymetry. Seismic reflections from within the shallow sediments are caused primarily by contrasts in density, rather than acoustic velocity. Reflections were successfully simulated using a model with a constant velocity of 1560 m/s and densities of 2.1 g/cc for sand, 1.4 g/cc for mud, and 1.7 g/cc for silty sand. The chirp sonar profiles imaged near-seafloor geology at nearly a meter scale and allowed for detailed interpretation. The interaction of soft sediment deformation, creep movement and neo-tectonic activity related to gas expulsion controlled the actual topography of the sea-floor. The geologic time represented in the 50 milliseconds of chirp data recorded with the AUV, which is about 40 meters of depth, is approximately 0.050 Ma. B.P., consistent with a depositional rate of 0.8 meters per 1000 years. Reflection patterns are interpreted to be related to fluctuations in sea level. High reflectivities (density contrasts) are interpreted to be deposited during the last sea level low stand, and low reflectivities are interpreted as sedimentation during the last high stand. Sediments deposited during the low stand are proximal while others are distal, deposited in deeper water environments. Shallow structures observed in the chirp sonar profiles are mainly related to gas mobilization mechanisms, which shaped the topography of the seafloor in conjunction with soft sediment deformation and creep movement. The geomorphic features are related in some cases to gas expulsion zones such as pockmarks and mud volcanoes. Other structures are related to soft sediment deformation and creep mobilization. Soft sediment deformation is confined to the deepest part of the minibasin, while the other features are not depth dependent. Highly deformed intervals at the bottom of the sequence seem to control subsequent sedimentation.Item Aquatic macrophyte and animal communities in a recently restored brackish marsh: possible influences of restoration design and the invasive plant species Myriophyllum spicatum(2012-07-16) Bell, Michael ThomasThe numerous benefits that wetlands provide make them essential to ecosystem services and ecological functions. Historically, wetland losses have been caused by natural and anthropogenic changes. In Texas, nearly 50% of coastal wetland habitat has been lost since the 1930s and losses in the Lower Neches watershed have been some of the most extensive. Restoration is a way to mitigate these losses and can be accomplished in many ways. Each restoration design creates different aquatic habitats that can influence both submerged aquatic vegetation (SAV) and faunal communities. The restoration of the Lower Neches Wildlife Management Area (LNWMA) has created the conditions for the growth of the invasive submerged macrophyte, Myriophyllum spicatum (Eurasian watermilfoil) which may be competing with the native aquatic grass, Ruppia maritima (widgeongrass) for essential nutrients. In this study, an attempt was made to link restoration design with both SAV and aquatic fauna community structures by using a throw trap to characterize assemblages observed in three different types of restored marshes. We also performed two controlled mesocosm experiments in 0.5 gal aquariums to determine growth inhibition by M. spicatum on R. maritima. Analyses using Kruskal-Wallis non-parametric test determined that temporal variations in fauna and SAV community composition was greater than any restoration effect. Discriminant Function Analyses (DFAs) determined two to three key faunal species that best predicted association among restoration designs, but linear regressions could not determine any consistent relationship between individual species density and biomass of the dominant SAV species, M. spicatum. For the mesocosm experiments, M. spicatum inhibited the biomass production and branch count of R. maritima when the two species are grown together (ANOVA, p = 0.004 and 0.003, respectively). Changes in SAV assemblages due to competition and habitat characteristics could play a major role in determining faunal community. In order to minimize the temporal effect observed and better determine any habitat pattern that may be present, a much longer study is necessary.Item Assessment of estuarine habitats for resident and estuarine-dependent species: tools for conservation and management(2009-05-15) Shervette, Virginia RheaMy research in coastal Ecuador and the northern Gulf of Mexico (GOM) elucidated differences in value of shallow estuarine habitats for fishes and invertebrates. I focused on mangrove and tidal river habitats in Ecuador, and oyster reef, vegetated marsh edge, and nonvegetated bottom habitats in the GOM. Coastal Ecuador has lost 20-30% of mangrove wetlands over the past 30 years. Such habitat loss can impair the ecological functions of wetlands. In this study I identified the fish community of the remaining mangrove wetland in Rio Palmar, Ecuador. For comparison, an adjacent tidal river without mangroves, Rio Javita, was also sampled. I found that although Rios Palmar and Javita are characterized by relatively low fish-species richness compared to other tropical estuarine systems, they appear to provide important habitat for several economically- and ecologically-valued species. In the GOM, I examined the fish and invertebrate communities of adjacent oyster reef (oyster), vegetated marsh edge (VME), and nonvegetated bottom (NVB) habitats. Three main relationships emerged: 1) Oyster and VME provide habitat for significantly more species (as a measure of richness) relative to NVB; 2) Oyster and VME provide habitat for uncommon and rare species; and 3) Many of the species collected in multiple habitats occurred at higher abundances in oyster or VME habitat. Contrary to the current low value ranking of oyster habitat relative to other estuarine and salt marsh habitats, oyster provides high quality habitat for many species. Understanding how key species utilize estuarine habitats is critical for future conservation and management efforts. My research indicated that VME habitat may provide better foraging options for juvenile pinfish (Lagodon rhomboides), and together with corroborating evidence from other studies, suggest that VME provides a critical nursery function for juvenile pinfish, especially in estuaries where seagrass habitat is sparse or nonexistent. Additionally, I documented that juvenile white shrimp (Litopenaeus setiferus) select for oyster habitat because of higher food availability and not because of refuge needs from predation by blue crabs. Oyster habitat appears to provide a nursery function for juvenile white shrimp. Overall, my research demonstrated that structurally complex habitats, such as mangroves, VME, and oyster provide essential habitat at the community, population, and individual levels.Item Assessment of seismic risk for subsea production systems in the Gulf of Mexico(Texas A&M University, 2004-09-30) Brown, Laura AnnThe number of subsea production systems placed in deepwater locations in the Gulf of Mexico (GOM) has increased significantly in the last ten to fifteen years. Currently, API-RP2A (2000 a,b) designates the GOM as a low seismic zone, and thus does not require seismic effects to be considered during the design process. However, there have been a number of seismic events with Richter magnitudes between 3.0 and 4.9 that have occurred in this region. As a result, questions have been raised regarding the seismic performance of deepwater subsea systems. This thesis presents an analytical parametric study where a prototype subsea structure was selected based on a survey of subsea systems. The baseline analytical model consisted of a single casing embedded in soft clay soils, which supported a lumped mass at a cantilevered height above the soil. A number of the model characteristics were varied in the parametric study to simulate the structural response of a range of subsea structures. This thesis discusses the impact of API-RP2A Zone 1 and 2 design seismic demands for the performance of subsea structures. The results from the subsequent analyses show that the stresses and deflections produced by the Zone 1 and 2 peak ground accelerations fall within the allowable limits.Item Bioaccumulation of mercury in pelagic fishes in NW Gulf of Mexico(Texas A&M University, 2006-08-16) Cai, YanTotal mercury (Hg) levels were determined in the tissues of ten taxa of pelagic fishes, with a special emphasis on apex predators (large vertebrates). Highest Hg levels were observed in blue marlin (Makaira nigricans), carcharhinid sharks (Genus Carcharhinus) and little tunny (Euthynnus alletteratus), ranging from 1.08 to 10.52 ppm. Moderate to low concentrations (<1.0 ppm) were observed in blackfin tuna (Thunnus atlanticus), cobia (Rachycentron canadum), dolphinfish (Coryphaena hippurus), greater amberjack (Seriola dumerili), king mackerel (Scomberomorus cavalla), wahoo (Acanthocybium solandri) and yellowfin tuna (Thunnus albacares). For the majority of species examined, Hg level did not vary significantly between locations (Texas and Louisiana) and years (2002 and 2003). The relationship between Hg level and fish size/weight was also explored and six taxa (blackfin tuna, carcharhinid sharks, dolphinfish, king mackerel, wahoo, yellowfin tuna) showed significant positive relationships between Hg level and body size and/or weight. Natural dietary tracers, stable isotopes (15N, 13C) and fatty acids were used to evaluate the relationship between Hg and trophic position and the relationship between Hg and dietary history. Stable nitrogen isotope analysis showed that Hg levels in fish tissues were positively associated with trophic position. Based on the 13C and 15N values of pelagic consumers examined in this study, three natural groups were identified with cluster analysis, and the same groupings were detected based on fatty acid profiles. This not only confirmed the existence of these natural groupings, but also indicated that the distinguishing factors for the grouping was likely connected with the dietary history of these fishes. The classification tree based on the fatty acid profiles of pelagic fishes readily separated fishes from different regions, suggesting that diets of pelagic taxa within the same region are similar or these consumers share a common source of organic matter in their food web. Findings from this study complement other Hg investigations conducted in the Gulf and also furthered our understanding of the link between feeding ecology and Hg accumulation. Moreover, the combined use of stable isotope and fatty acid techniques provided new insights on the dietary history of pelagic fishes in the Gulf of Mexico.Item Black mangrove (Avicennia sp.) colony expansion in the Gulf of Mexico with climate change : implications for wetland health and resistance to rising sea levels(2010-12) Comeaux, Rebecca Suzanne; Allison, Mead A. (Mead Ashton); Bianchi, Thomas S.; Mohrig, David; Wilson, Clark R.Populations of black mangroves (Avicennia sp.) are hypothesized to expand their latitudinal range with global climate change in the 21st century, induced by a reduction in the frequency and severity of coastal freezes, which are known to limit mangrove colony extent and individual tree size, as well as an overall warmer climate. The Gulf of Mexico is located at the northward limit of black mangrove habitat and is therefore a prime candidate for population expansion with global warming. This expansion may come at the expense of existing Gulf coastal saline wetlands that are dominantly Spartina spp. marsh grasses. The present study was conducted to focus, not on the extent to date of this replacement, but to examine the potential implications of a marsh to mangrove transition in Gulf wetlands, specifically 1) resistance to accelerating eustatic sea level rise (ESLR) rates, 2) wetland resistance to wave attack in large storms (increased cyclonic storm frequency/intensity is predicted with future climate warming), and 3) organic carbon sequestration and wetland soil geochemistry. Field sites of adjacent and intergrown Avicennia mangrove and Spartina marsh populations in similar geomorphological setting were selected in back-barrier areas near Port Aransas and Galveston, TX (two sites each) as part of a larger-scale planned study of the full latitudinal transition of the western Gulf funded by the National Institute for Climate Change Research (U.S. Department of Energy). The reconnaissance conducted for site surveys show that black mangrove populations in this part of Texas are clustered near inlet areas, suggesting seed transport vectors are a major control on colony establishment, and likely, on the potential rapidity of wetland habitat replacement. Resistance to ESLR was tested by 1) creating high-accuracy (±1 cm) elevation maps over ~5,000 m² areas of adjacent mangrove and marsh areas, and 2) measuring mineral and organic matter accumulation rates (Pb/Cs radiotracer geochronology, loss on ignition) from auger cores. Elevation surveys in Port Aransas indicate mangrove vegetated areas are 4 cm higher in elevation than surrounding marsh on an average regional scale, and 1 to 2 cm higher at the individual mangrove scale: at the Galveston sites, any trend is complicated by the area's pre-existing geomorphology and the relative youth of the mangrove colonies. ¹³⁷Cs accumulation rates and loss on ignition data indicate that mineral trapping is 4.1 times higher and sediment organics are 1.7 times lower in mangroves at Port Aransas; no such definable trends exist at the Galveston sites or in calculated ²¹⁰Pb sediment accumulation rates. This additional mineral particle trapping in mangroves does not differ in grain size character from marsh mineral accumulation. Elevation change may also be effected by root volume displacement: live root weight measurements in the rooted horizon (~0 to 20 cm depth) are consistently higher in mangrove cores from Port Aransas and the site at the west end of Galveston Island. Port Aransas porosities are lower in mangrove rooted horizons, with a corresponding increase in sediment strength (measured by shear vane in the cores), suggesting mangrove intervals may be more resistant to wave-induced erosion during storm events. Port Aransas mangroves exhibit higher pore water redox potentials and salinities over entire core depths and depressed pH over rooted intervals, suggesting a distinct diagenetic environment exists relative to marsh sites. Increased salinities and higher redox potentials may be a function of the rooting network, which introduces oxygen into the sediment and focuses evapo-transpiration and salt exclusion within this zone: this may prove advantageous when competing with marsh grasses by elevating salinities to levels that are toxic for Spartina. Trends observed in the more mature systems of Port Aransas are generally absent at the Galveston sites, suggesting the youth and physically shorter stature of these systems means they have not yet established a unique sediment signature.Item Centennial-Scale Sea Surface Temperature and Salinity Variability in the Florida Straits During the Early Holocene(2012-10-19) Weinlein, WilliamPrevious studies showed that sea surface salinity (SSS) in the Florida Straits as well as Florida Current transport covaried with changes in North Atlantic climate over the past two millennia. However, little is known about earlier Holocene variability in the Florida Straits. Here, we combine Mg/Ca-paleothermometry and stable oxygen isotope measurements on the planktonic foraminifera Globigerinoides ruber (white variety) from Florida Straits sediment core KNR166-2 JPC 51 (24 degrees 24.70? N, 83 degrees 13.14?W, 198m deep) to reconstruct a high-resolution (~30 yr/sample) early to mid Holocene record of sea surface temperature and delta18OSW (a proxy for SSS) variability. We also measured Ba/Ca ratios in the same shell material as a proxy for riverine input into the Gulf of Mexico over the same time interval. After removing the influence of global delta18OSW change due to continental ice volume variability, we propose that early Holocene SSS enrichments were caused by increased evaporation/precipitation ratios in the Florida Straits associated with periods of reduced solar output, increased ice rafted debris in the North Atlantic and the development of more permanent El Nino-like conditions in the eastern equatorial Pacific. When considered with previous high-resolution reconstructions of early Holocene tropical atmospheric circulation changes, our results provide evidence that solar output variability over the Holocene had a significant impact on the global tropical hydrologic cycle over the last 10,000 years.Item Characteristics of the deep scattering layer in the Gulf of Mexico as they relate to sperm whale diving and foraging behavior(2009-05-15) Azzara, Alyson JulieThis research was carried out in support of fieldwork in the Gulf of Mexico in summers 2004 and 2005 as part of the multidisciplinary Sperm Whale Seismic Study (SWSS). Important aspects of SWSS research include oceanographic habitat characterization and studies of sperm whale foraging and diving patterns. During the SWSS 2005 cruise, acoustic volume backscatter data were collected using a 38 kHz ADCP for comparison with XBT, MODIS ocean color data, and whale dive profiles extrapolated from analysis of towed passive acoustic hydrophone array recordings of whale vocalizations. This unique data set, collected from a cyclonic eddy, was compared with non-upwelling conditions surveyed in the western Gulf and the Mississippi Canyon in summer 2004. My focus was to examine the relationship between acoustic backscatter intensity from the deep scattering layer (DSL; usually 400-600 m deep) and the depths to which whales dived. The results of the study investigate differences in DSL characteristics between divergent zones and non-divergent zones, and examine connections relating to variations in sperm whale dive patterns. The analysis of 38 kHz ADCP data showed that there were significant differences in some characteristics of the main DSL dependent on time of day. There were no significant differences in characteristics of the main DSL between divergent and non-divergent areas or between 2004 and 2005. The comparison of the 38 kHz ADCP and the 70 kHz Simrad echosounder data yielded a relationship of 4 ADCP counts for every 1 dB of Sv. This relationship was a promising start to a potential calibration for the ADCP instrument. Lastly, the analysis of localized sperm whale dive profiles identified three basic dive profiles; Deep (> 800 m), Mid-water dives to DSL depths (500 - 800 m) and Shallow (<500 m). The analysis also showed that whale dive behavior did not change based on time of day or location. It showed that whales are diving above the DSL as well as through and below, however these dives are independent of differences in DSL characteristics.Item Characteristics of undrained shear strength in shallow soils in deep water Gulf of Mexico(2013-05) West, James William; Gilbert, Robert B. (Robert Bruce), 1965-Shallow foundations are used when designing subsea structures on the seafloor of deep water Gulf of Mexico. In order to design these subsea shallow foundations it is important to understand the behavior of the undrained shear strength of the shallow soils (i.e. upper ten to twenty feet of soil). The objective of this research is to analyze a database of soil data from deep water Gulf of Mexico originally produced by Cheon (2011) with a focus on shallow soils. The purpose of this analysis is to gain a better understanding of the soil and how it will be usable with regards to shallow foundation design. The methodology of this analysis involves studying raw data collected from different measurements taken to aid in the creation of design profiles of undrained shear strength versus depth. Within the existing database there are 18 locations with a high resolution of point data from in-situ tests (Halibut Vane) and non in-situ tests (Minivane and Torvane) that provide the clearest picture of undrained shear strength in the shallow region. The data shows that the design profiles originally created for these locations for deep foundations are generally not representative of the strength in the shallow region. They also show that in-situ test data show more variability than non in-situ data. There are also 25 Cone Penetration Tests in the existing database that show very high resolution data in the shallow region. These Cone Penetration Tests also indicate a crust that appears to be about 1 ft thick and exists along the edge of the continental shelf. Recommended future activities to build upon this work include re-evaluating the design profiles at these 43 locations at which high resolution studies have been performed in the shallow region, collecting these design profiles as well as any new design profiles and organizing them into a new database focused on shallow soils, generating a new generic profile base on the data within the new database, and creating a model that uses spatial variability analysis to calculate undrained shear strengths at new locations based on the data in the database.Item Characterizing the petrophysical properties of shallow marine environments and their potential as methane hydrate reservoirs(2015-05) Nole, Michael Anthony; Daigle, Hugh; Mohanty, KishoreIn shallow marine sedimentary environments, characterization of sediment petrophysical and thermodynamic properties is imperative for understanding the subsurface transport of fluids and their chemical constituents. This work first presents an objective method of scanning electron microscope image analysis that directly quantifies microporosity in clay-rich, fine-grained sediments typical of the shallow marine subsurface. The method is powerful because it is fast, easy, and provides a direct microporosity estimation technique to augment or replace experimental data. When used appropriately, the method can be implemented on microporous sediments and sedimentary rock in general. With an understanding of how microporosity manifests in shallow marine sediments, the impact of small pore sizes on methane hydrate solubility is then examined for core samples taken from 3 sites in the Nankai Trough offshore Japan, an area that has been heavily surveyed in recent years for its potential to host economically recoverable deposits of methane hydrate for use as a natural gas resource. Small pores in fine-grained shaley intervals are shown to significantly increase the aqueous solubility of methane in pore water relative to surrounding coarser-grained sediment strata, which can have broad implications for methane hydrate formation, including lack of formation in the clayey intervals and strong diffusive fluxes of methane into coarser sediment layers. Finally, an existing methane hydrate reservoir simulator is modified to model methane hydrate accumulations in marine environments with heterogeneous layered sediments. The impact of pore size on solubility is included in the model along with steady state microbial methanogenesis and diffusion of salt in the pore water. The simulator is then used to successfully model methane hydrate accumulations in 1D and 2D at Walker Ridge Site 313 in the Gulf of Mexico, where well logs and seismic surveys throughout the region abound. This work is an important step in building a general 3D methane hydrate reservoir simulator for shallow marine environments around the globe.Item Characterizing the Weather Band Variability of the Texas Coastal Current(2014-07-17) Zimmerle, HeatherCurrent velocities from 21 years (1992-2012) of near-continuous observations are used to investigate the Texas Coastal Current on the western Texas-Louisiana continental shelf in the northwestern Gulf of Mexico. Observations were made using the moored current meters deployed as part of the Texas Automated Buoy System (TABS) and historical current meter data. The general coastal circulation is known to be deterministic, with downcoast flow (westward) in the non-summer months (September-May) and a reversal to upcoast (eastward) flow in the summertime (June-August). This study focuses on characterizing features of the Texas Coastal Current that include the onset, frequency, magnitude, and persistence of current reversals along with the upcoast transport that occurs during reversals. The determined interannual variability of the Texas Coastal Current is imperative for understanding the surface transport of water and mitigating associated coastal hazards, including oil, harmful algal blooms, and hypoxia. Results show the onset of the upcoast reversal during the summer with a mostly downcoast flow during the non-summer at upper Texas coastal locations. More persistent currents are observed during the non-summer in the downcoast direction within the weather band frequencies (2-15 days). Currents with longer persistence are found to be relatively slow, generally below 10 cm s^(-1). Fast currents (> 50 cm s^(-1)) tend to be short-lived, typically lasting less than 72 hours. Maximum upcoast transport is observed along the upper coast during the summer, reaching a minimum in the winter and fall. A relationship between the along-shore wind stress and along-shore current velocity is indicated, signaling that the Texas Coastal Current is mostly wind-driven. Spatial variability is present along the southern Texas coast. Current flow is directed downcoast during the summer and slightly downcoast during the non-summer at buoy J, the southernmost location. Currents near the coastal bend tend to be upcoast during the non-summer and slightly downcoast during the summer. Longer persistence is observed at the southern location in the downcoast direction during the summer, with several currents lasting longer than 15 days. Maximum upcoast transport is present during the winter along the southern Texas Coast, reaching a minimum during the summer. Some evidence of a relationship between the along-shore wind stress and along-shore current flow are present, indicating some wind-driven forcing on the current flow. Less seasonal variability is present at offshore locations. Locations on the outer shelf display a general upcoast flow regardless of season. Longer persistence is observed in the upcoast direction on the outer shelf during the summer and non-summer. Maximum upcoast transport is present during the non-summer at all offshore locations. Little correlation is found between seasonal winds and along-shore current flow, meaning mesoscale features, such as Loop Current eddies, provide offshore current forcing.Item Coastal and Marine Nitrogen Sources Shift Isotopic Baselines in Pelagic Food Webs of the Gulf of Mexico(2012-07-16) Dorado, SamuelUpwelling, atmospheric nitrogen (N2) fixation by cyanobacteria, and freshwater inputs from the Mississippi River system have been shown to stimulate new production by alleviating nitrogen (N) limitation in the northern Gulf of Mexico (GoM). Stable carbon (delta13C) and nitrogen (delta15N) isotopes were used to investigate whether these sources are utilized differentially by coastal and marine pelagic food webs. Particulate organic matter (POM), Trichodesmium, and zooplankton were collected from the Mississippi River plume and Loop Current (LC) which were detected using remote sensing data. Stable isotope values were used to separate coastal and marine water masses and environmental data (salinity, nutrient and pigment concentrations) allowed me to relate variability to the degree of freshwater influence. Published food web data from these two environments were then assessed to establish whether isotopic baseline shifts observed in our data occur at an ecosystem level. Isotope values of the POM and zooplankton were found to be significantly different between coastal and marine water masses. This was not the case for Trichodesmium whose isotope values were not significantly different between the two water masses. We found that marine water masses (sal > 35) exhibited silicate concentrations, cyanobacterial pigments and DIN: P that suggest an increased abundance of diazotrophs. In contrast, coastal water masses (sal < 35) exhibited increased diatom pigments and molar C:N indicating terrestrial sources fuel phytoplankton production. When published food web data were compared, we found producer and consumer delta15N values were enriched in the coastal compared to the marine environments. This work suggests that differences in delta15N values within my data set and published data reflect a shift in the use of biologically available N where higher trophic levels are sustained by diazotrophic activity in marine environments versus those supported by terrestrial sources in coastal ones. Food webs that have been constructed without considering Trichodesmium as a significant source of organic matter in the GoM should be reconsidered. By re-evaluating published data, this research gives insight into the early life ecology of larval fishes and works to help answer questions about the structure and function of pelagic food webs.Item Coastal Hypoxia on the Texas Shelf: An Ocean Observing and Management Approach to Improving Gulf of Mexico Hypoxia Monitoring(2013-05-07) Mullins, Ruth LouiseA combination of in situ sampling and real-time ocean observations was used to investigate the processes responsible for the formation and the areal extent of Texas coastal hypoxia from 2002 to 2011. In situ sampling, real-time mooring and buoy observations, and multivariate statistical modeling were used to investigate the physical processes driving hypoxia formation. Geostatistical interpolation (ordinary kriging) models were tested to compare the differences in annual hypoxia area on the Texas shelf. Results from these two sections were integrated into recommendations for improving federal hypoxia monitoring and mitigation strategies in the northwestern Gulf of Mexico. Winds, currents, temperature, salinity, and dissolved oxygen records revealed the annual, seasonal, and daily variability of hypoxia formation on the Texas coast from 2009 to 2011. Hypoxic events occurred from late May to late October lasting from hours to weeks. Hypoxia formation was either the result of salinity stratification, associated with the freshening of surface waters by the advection of Mississippi-Atchafalaya River freshwater westward or the wind- and current-driven upcoast or downcoast flow of Brazos River discharge. Records from 2010 and 2011 showed the variability and frequency of stratification development differs on the north and south Texas shelf. Multivariate linear model results showed contributing factors on the north Texas shelf vary annually and that primary factors for hypoxia development are near-surface current speeds and salinity-driven stratification. Interpolation models resulted in three size categories for hypoxia area: small (100 ? 1,000 km^2), moderate (1,001 ? 3,000 km^2), and large (3,001+ km^2). Moderate years include 2002, 2004, and 2007 and a large year was 2008. There was no increase in hypoxic area from years 2002 to 2011, but years 2007 and 2008 resulted in a hypoxic area over 5,000 km^2, which is the federally mandated hypoxia reduction target for the northwestern Gulf of Mexico. Geostatistical interpolators represent and predict the structure and spatial extent of the hypoxic area on the Texas shelf by accounting for the anisotropy of physical processes on the Texas shelf. Geostatistical interpolation models are preferred to deterministic models for developing and improving federal hypoxia monitoring and mitigation strategies on the northwestern Gulf of Mexico shelf.Item Community structure of deep-sea bivalve mollusks from the northern Gulf of Mexico(Texas A&M University, 2004-09-30) Chen, MinDensity, species diversity, species richness, and evenness of bivalve mollusks were measured in the deep (0.2km to 3.7km) northern Gulf of Mexico to describe the community structure of benthic bivalve mollusks. Density decreased gradually from shallow continental slope depths, with remarkably high values in the Mississippi canyon, to the deepest sites. Diversity of bivalve mollusks increased from shallow continental slope depths, with low values in the Mississippi canyon, to a maximum at intermediate depths (1-2km), followed by a decrease down to the deepest locations (3.7km). Nine distinct groups were formed on the basis of the similarity in species composition. The pattern varied more abruptly on the slope compared to the deeper depths, possibly due to steeper gradients in physical variables. ANOVA indicated that the density of bivalve mollusks was not significantly different at different depths, was not significantly different on different transects, was not significantly different between basin and non-basin, but was significantly different in canyon and non-canyon locations. Similar distinctions were observed in diversity, except that basins were lower than non-basins. The patterns observed reflect the intense elevated input of terrigenous sediments accompanied by high surface-water plankton production from the Mississippi River to the north central gulf.Item Compressibility and permeability of Gulf of Mexico mudrocks, resedimented and in-situ(2014-05) Betts, William Salter; Flemings, Peter Barry, 1960-Uniaxial consolidation tests of resedimented mudrocks from the offshore Gulf of Mexico reveal compression and permeability behavior that is in many ways similar to those of intact core specimens and field measurements. Porosity (n) of the resedimented mudrock also falls between field porosity estimates obtained from sonic and bulk density well logs at comparable effective stresses. Laboratory-prepared mudrocks are used as testing analogs because accurate in-situ measurements and intact cores are difficult to obtain. However, few direct comparisons between laboratory-prepared mudrocks, field behavior, and intact core behavior have been made. In this thesis, I compare permeability and compressibility of laboratory-prepared specimens from Gulf of Mexico material to intact core and field analysis of this material. I resediment high plasticity silty claystone obtained from Plio-Pleistocene-aged mudrocks in the Eugene Island Block 330 oilfield, offshore Louisiana, and characterize its compression and permeability behavior through constant rate of strain consolidation tests. The resedimented mudrocks decrease in void ratio (e) from 1.4 (61% porosity) at 100 kPa of effective stress to 0.34 (26% porosity) at 20.4 MPa. I model the compression behavior using a power function between specific volume (v=1+e) and effective stress ([sigma]'v): v=1.85[sigma]'v-⁰̇¹⁰⁸. Vertical permeability (k) decreases from 2.5·10-¹⁶ m² to 4.5·10-²⁰ m² over this range, and I model the permeability as a log-linear function of porosity (n): log₁₀ k=10.83n - 23.21. Field porosity estimates are calculated from well logs using two approaches; an empirical correlation based on sonic velocities, and a calculation using the bulk density. Porosity of the resedimented mudrock falls above the sonic-derived porosity and below the density porosity at all effective stresses. Measurements on intact core specimens display similar compression and permeability behavior to the resedimented specimens. Similar compression behavior is also observed in Ursa Basin mudrocks. Based on these similarities, resedimented Gulf of Mexico mudrock is a reasonable analog for field behavior.Item Cooperative binational coastal zone management : recommendations for Texas and Tamaulipas(2006-05) Barraza Lizárraga, Eleonor; Butler, Kent S.The Gulf of Mexico is a shared resource at risk. It is facing many problems such as exponential population growth, degrading water quality, consequences of oil and gas activities, unsustainable exploitation of resources, and lack of public education and political interest. In response, Mexico and the United States have devised their own set of programs and strategies to best manage their coastal zones. There have been a few official coastal management efforts between the U.S. Gulf states and Mexico. However, the existence of these collaborative programs does not supplant the need for a binational, integrated coastal management effort. Texas and Tamaulipas have participated in these cooperation programs, but direct coastal collaboration between the two states has been limited. Although there is an obvious disparity between the two regarding CZM practices, both states face similar challenges that require a cooperative effort and combined resources. This report explores different alternatives for binational cooperation between Texas and Tamaulipas at the regional level, in the context of the existing CZM frameworks and strategies of each state.