Browsing by Subject "Flammability limits"
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Item Flammability Characteristics of Hydrogen and Its Mixtures with Light Hydrocarbons at Atmospheric and Sub-atmospheric Pressures(2013-07-13) Le, Thuy Minh HaiKnowledge of flammability limits is essential in the prevention of fire and explosion. There are two limits of flammability, upper flammability limit (UFL) and lower flammability limit (LFL), which define the flammable region of a combustible gas/vapor. This research focuses on the flammability limits of hydrogen and its binary mixtures with light hydrocarbons (methane, ethane, n-butane, and ethylene) at sub-atmospheric pressures. The flammability limits of hydrogen, light hydrocarbons, and binary mixtures of hydrogen and each hydrocarbon were determined experimentally at room temperature (20?C) and initial pressures ranging from 1.0 atm to 0.1 atm. The experiments were conducted in a closed cylindrical stainless steel vessel with upward flame propagation. It was found that the flammable region of hydrogen initially widens when the pressure decreases from 1.0 atm to 0.3 atm, then narrows with the further decrease of pressure. In contrast, the flammable regions of the hydrocarbons narrow when the pressure decreases. For hydrogen and the hydrocarbons, pressure has a much greater impact on the UFLs than on the LFLs. For binary mixtures of hydrogen and the hydrocarbons, the flammable regions of all mixtures widen when the fraction of hydrogen in the mixture increases. When the pressure decreases, the flammable regions of all mixtures narrow. The applications of Le Chatelier?s rule and the Calculated Adiabatic Flame Temperature (CAFT) model to the flammability limits of the mixtures were verified. It was found that Le Chatelier?s rule could predict the flammability limits much better than the CAFT model. The adiabatic flame temperatures (AFTs), an important parameter in the risk assessment of fire and explosion, of hydrogen and the hydrocarbons were also calculated. The influence of sub-atmospheric pressures on the AFTs was investigated. A linear relationship between the AFT and the corresponding flammability limit is derived. Furthermore, the consequence of fire relating to hydrogen and the hydrocarbons is discussed based on the AFTs of the chemicals.Item Inert Gas Dilution Effect on the Flammability Limits of Hydrocarbon Mixtures(2012-02-14) Zhao, FumanFlammability limit is a most significant property of substances to ensure safety of chemical processes and fuel application. Although there are numerous flammability literature data available for pure substances, for fuel mixtures these are not always available. Especially, for fuel mixture storage, operation, and transportation, inert gas inerting and blanketing have been widely applied in chemical process industries while the related date are even more scarce. Lower and upper flammability limits of hydrocarbon mixtures in air with and without additional nitrogen were measured in this research. Typically, the fuel mixture lower flammability limit almost keeps constant at different contents of added nitrogen. The fuel mixture upper flammability limit approximately linearly varies with the added nitrogen except mixtures containing ethylene. The minimum added nitrogen concentration at which lower flammability limit and upper flammability limit merge together is the minimum inerting concentration for nitrogen, roughly falling into the range of 45 plus/minus 10 vol % for all the tested hydrocarbon mixtures. Numerical analysis of inert gas dilution effect on lower flammability limit and upper flammability limit was conducted by introducing the parameter of inert gas dilution coefficient. Fuel mixture flammability limit can be quantitatively characterized using inert gas dilution coefficient plus the original Le Chatelier's law or modified Le Chatelier's law. An extended application of calculated adiabatic flame temperature modeling was proposed to predict fuel mixture flammability limits at different inert gas loading. The modeling lower flammability limit results can represent experimental data well except the flammability nose zone close to minimum inerting concentration. Le Chatelier's law is a well-recognized mixing rule for fuel mixture flammability limit estimation. Its application, unfortunately, is limited to lower flammability limit for accurate purpose. Here, firstly a detailed derivation was conducted on lower flammability limit to shed a light on the inherent principle residing in this rule, and then its application was evaluated at non-ambient conditions, as well as fuel mixture diluted with inert gases and varied oxygen concentrations. Results showed that this law can be extended to all these conditions.