Browsing by Subject "Electrical resistivity"
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Item Groundwater flow controls on coastal water quality and global groundwater ages(2015-05) Befus, Kevin Martin; Cardenas, Meinhard Bayani, 1977-; Gleeson, Thomas P; Hesse, Marc A; Paine, Jeffrey G; Sharp, John MHumanity relies on groundwater. But, current consumption may be outpacing groundwater renewal rates, and anthropogenic activities are altering its quality. This dissertation advances the state of knowledge of how local and regional groundwater dynamics affect its quality and quantity. First, I investigate groundwater discharge patterns and fluxes in three lakes in the Nebraska Sand Hills region and on the island of Rarotonga, Cook Islands, to understand the hydrologic connection between groundwater and surface water in these lacustrine and coastal settings. In Nebraska, I use electrical geophysical methods to characterize the spatial signature of groundwater recharge and discharge to and from the lakes using groundwater salinity patterns. On Rarotonga, a detailed field study of groundwater flow at the intertidal zone shows how groundwater flow influences the thermal regimes of nearshore environments, affecting the biota that live and chemical processes that occur near and below this dynamic interface. Next, a dense network of geophysical surveys across the coastal plain and into the lagoon on Rarotonga constrains multiple features of the larger-scale hydrologic system that are primarily controlled by the local carbonate and volcanic geology on the island. Finally, I give the first estimate of the global storage and spatial distribution of groundwater with a mean age since recharge of less than fifty years. I use several thousand two-dimensional groundwater flow and age-as-mass transport simulations parameterized by the best available hydrologic and geologic datasets. This global analysis suggested that ~6% of the groundwater stored in the upper 2 km of the Earth’s crust is younger than 50 years. Comparing this young groundwater storage to current groundwater depletion rates indicates that more than half of the irrigated areas depending significantly on groundwater could have already used up all of the young groundwater and are using groundwater more quickly than the storage is replenished. Together, these studies advance how to quantify groundwater as a renewable resource through the global estimation of groundwater storage associated with certain timespans and by analyzing the implications of groundwater flow on water quantity and quality in field settings.Item Pore-scale numerical modeling of petrophysical properties with applications to hydrocarbon-bearing organic shale(2013-12) Shabro, Vahid; Torres-Verdín, Carlos; Sepehrnoori, Kamy, 1951-The main objective of this dissertation is to quantify petrophysical properties of conventional and unconventional reservoirs using a mechanistic approach. Unconventional transport mechanisms are described from the pore to the reservoir scale to examine their effects on macroscopic petrophysical properties in hydrocarbon-bearing organic shale. Petrophysical properties at the pore level are quantified with a new finite-difference method. A geometrical approximation is invoked to describe the interstitial space of grid-based images of porous media. Subsequently, a generalized Laplace equation is derived and solved numerically to calculate fluid pressure and velocity distributions in the interstitial space. The resulting macroscopic permeability values are within 6% of results obtained with the Lattice-Boltzmann method after performing grid refinements. The finite-difference method is on average six times faster than the Lattice-Boltzmann method. In the next step, slip flow and Knudsen diffusion are added to the pore-scale method to take into account unconventional flow mechanisms in hydrocarbon-bearing shale. The effect of these mechanisms is appraised with a pore-scale image of Eagle Ford shale as well as with several grain packs. It is shown that neglecting slip flow in samples with pore-throat sizes in the nanometer range could result in errors as high as 2000% when estimating permeability in unconventional reservoirs. A new fluid percolation model is proposed for hydrocarbon-bearing shale. Electrical conductivity is quantified in the presence of kerogen, clay, hydrocarbon, water, and the Stern-diffuse layer in grain packs as well as in the Eagle Ford shale pore-scale image. The pore-scale model enables a critical study of the [delta]LogR evaluation method commonly used with gas-bearing shale to assess kerogen concentration. A parallel conductor model is introduced based on Archie's equation for water conductivity in pores and a parallel conductive path for the Stern-diffuse layer. Additionally, a non-destructive core analysis method is proposed for estimating input parameters of the parallel conductor model in shale formations. A modified reservoir model of single-phase, compressible fluid is also developed to take into account the following unconventional transport mechanisms: (a) slip flow and Knudsen diffusion enhancement in apparent permeability, (b) Langmuir desorption as a source of gas generation at kerogen surfaces, and (c) the diffusion mechanism in kerogen as a gas supply to adsorbed layers. The model includes an iterative verification method of surface mass balance to ensure real-time desorption-adsorption equilibrium with gas production. Gas desorption from kerogen surfaces and gas diffusion in kerogen are the main mechanisms responsible for higher-than-expected production velocities commonly observed in shale-gas reservoirs. Slip flow and Knudsen diffusion marginally enhance production rates by increasing permeability during production.