Browsing by Author "Xu, Chen"
Now showing 1 - 4 of 4
Results Per Page
Sort Options
Item Exploring Volunteered Geographic Information (VGI) for Emergency Management: Toward a Wiki GIS Framework(2011-10-21) Xu, ChenThe past three years have witnessed unprecedented growth of user-generated volunteered geographic information (VGI) on the Web. Although scholars, decision makers, and citizens have recognized the potential value of VGI in emergency management, there exists no rigorous study on the availability, quality, and feasibility of VGI for applications related to emergency management. This dissertation applies methodologies of GIScience and computer science to present an overview of VGI and explore its value in emergency management with the goal of developing a wiki GIS approach for community emergency preparedness. This dissertation research concludes that VGI and wiki GIS represent new development in public participation in the production and use of geographic information. In emergency management, VGI and wiki GIS suggest a new approach to incorporate the general public in emergency response activities. By incorporating VGI in emergency management, official agencies and the general public gain better situational awareness in emergency management.Item Hydraulic Modeling of Large District Cooling Systems for Master Planning Purposes(Texas A&M University, 2007-09-17) Xu, ChenDistrict Cooling Systems (DCS) have been widely applied in large institutions such as universities, government facilities, commercial districts, airports, etc. The hydraulic system of a large DCS can be complicated. They often stem from an original design that has had extensive additions and deletions over time. Expanding or retrofitting such a system involves large capital investment. Consideration of future expansion is often required. Therefore, a thorough study of the whole system at the planning phase is crucial. An effective hydraulic model for the existing DCS will become a powerful analysis tool for this purpose. Engineers can use the model to explore alternative system configurations to find an optimal way of accommodating the DCS hydraulic system to the planned future unit. This thesis presents the first complete procedure for the use of commercial simulation software to construct the hydraulic model for a large District Cooling System (DCS). A model for one of the largest DCS hydraulic systems in the United States has been developed based on this procedure and has been successfully utilized to assist its master planning study.Item Molecular Level Characterization and Mobility of Radionuclide-Carrying Natural Organic Matter in Aquatic Environments(2012-10-19) Xu, ChenRadionuclides, 129I and 239,240Pu, are major products or by-products of nuclear fission and among the top risk drivers for waste disposal at the Savannah River Sites (SRS) and Rocky Flats Environmental Technology Sites (RFETS), respectively, due to their perceived mobility in the environment, excessive inventory, toxicity, and long half-life. The objective of this study is to investigate the role of natural organic matter in retarding or facilitating the migration of 129I and 239,240Pu in the Department of Energy (DOE) sites. Measurements of 127I and 129I in humic acids (HAs) and fulvic acids (FAs) obtained by five successive alkaline, two glycerol and one citric acid-alkaline extractions, demonstrated that these extractable humic substances (HS) together account for 54-56 percent and 46 percent of the total 127I and 129I in the soil, respectively. The variations among 127I and 129I concentrations, isotopic ratios (129I/127I), chemical properties of all these humic substances indicated iodine was bound to a small-size aromatic subunit (~10 kDa), while the large-size subunit (~90 kDa), which likely linked the small-size unit through some weak chemical forces, determined the relative mobility of iodine bound to organic matter. Soil resuspension experiments simulating surface runoff or stormflow and erosion events were conducted with soils collected from SRS. Results showed that 72-77 percent of the newly-introduced I- or IO3- were irreversibly sequestered into the organic-rich soil, while the rest was transformed into colloidal and dissolved organo-iodine by the soil. The resulting iodine remobilization contradicts the conventional view that considers only I- or IO3- as the mobile forms. Quantitative structure analysis by 13C DPMAS NMR and solution state 1H NMR on these humic substances indicate that iodine is closely related to the aromatic regions containing esterified products of phenolic and fomic acid or other aliphatic carboxylic acids, amide functionalities, quinone-like structure activated by electron-donating groups (e.g., NH2) or hemicelluloses-lignin-like complex with phenyl-glycosidic linkage. The micro-molecular environment, such as the hydrophobic aliphatic periphery hindering the active aromatic cores and the hydrophilic polysaccharides favoring its accessibility towards hydrophilic iodine species, play another key role in the interactions between iodine and SOM. NMR spectra of the colloidal organic Pu carrier which can potentially be released from the soil during the surface runoff or stormflow showed Pu was transported, at sub-pM concentrations, by a cutin-derived soil degradation products containing siderophore-like moieties and virtually all mobile Pu.Item Optimized procedures for extractioin, purification and characterization of exopolymeric substances (eps) from two bacteria (sagittula stellata and pseudomonas fluorescens biovar ii) with relevance to the study of actinide binding in aquatic environments(2009-05-15) Xu, ChenThe extracellular polymeric substances (EPS) of marine bacterium Sagittula stellata and soil bacterium Pseudomonas fluorescens Biovar II, were extracted by six methods referred to the bibliography, efficacies of which were compared based on the EPS yield, composition as well as cell disturbance. Purification methods on these EPS were also improved, which proved to be more cost-effective and involve less interference from broth, compared to previous methods. Size exclusion chromatography (SEC) proved to be a useful tool, providing the ?fingerprints? of the EPS extracted by different methods or after each purification step. Studies of the EPS production and composition at different growth stages provided abundant information and a basis for further in-depth studies. Results from SEC demonstrated that bacterial EPS had a constant molecular weight distribution all through the life but with various polymers in different proportions. Three fractions were successfully isolated by a combination of SEC and anion exchange chromatography for ?non-attched? EPS produced by Pseudomonas flurorescens Biovar II. Protein turned out to be a major component of EPS in their native states, which was mixed with the broth material and couldn?t be recognized previously. The EPS harvested at the optimal time of the bacterial life was purified according to the improved method and was more enriched in polysaccharides, with small amounts of proteins, giving the molecules amphiphilic properties. In addition, simultaneous determination of neutral sugars and uronic acids by GC-EI-MS provided more information on the monosaccharide composition of the exopolysaccharides. Isoelectric focusing (IEF) spectra of the bacterial EPS spiked with Pu/Th, and Pu-enriched Rocky Flats Environmental Technology Site (RFETS) soil organic colloid spiked with Th showed similar activity distributions of both actinides along the pH gradient, with the activities of both actinides focusing on the low pH region. Characterizations of this Pu-enriched IEF extract from RFETS soil by spectrophotometric methods and ATR-FTIR indicated the co-presence of lipids, proteins and polysaccharides, in contrast to the bacterial EPS, which showed a simpler composition. This suggests that Th/Pu binding to organic macromolecules is more determined by the availability of binding functional groups rather than the exact specific compounds.