Classical and quasiclassical trajectory calculations of ozone isotopomer formation in atomic oxygen and molecular oxygen collisions

Date

2002-08

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Texas Tech University

Abstract

In the present study, the ozone formation rate is determined using the calculated O3 survival time (ST) distribution explicitly rather than an average lifetime. This approach has the advantage of not constraining the PM dependence of ke6 by any assumptions about the nature of the ST distribution. The present chapter will be confined principally to modeling the absolute rate of ozone formation over the broad range of temperature (T = 130 - 370 K) and density (PM = 10^18 - 10^22 cm^-1 for which experimental information is available[10, 22, 23, 29, 32, 1].

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